dc.contributor.author | Nakane, N. | en |
dc.contributor.author | Nicolaïdes, Andrew N. | en |
dc.contributor.author | Tomioka, H. | en |
dc.contributor.author | Asato, A. E. | en |
dc.contributor.author | Liu, R. S. H. | en |
dc.creator | Nakane, N. | en |
dc.creator | Nicolaïdes, Andrew N. | en |
dc.creator | Tomioka, H. | en |
dc.creator | Asato, A. E. | en |
dc.creator | Liu, R. S. H. | en |
dc.date.accessioned | 2019-11-21T06:21:39Z | |
dc.date.available | 2019-11-21T06:21:39Z | |
dc.date.issued | 2006 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55886 | |
dc.description.abstract | IR spectra of α-cyano- o -fluorocinnamonitrile, its vinyl deuterated analogue and the corresponding photoproducts were recorded under Ar matrix isolation conditions (13K). An analysis of the IR spectra, assisted by calculations of the expected absorption signals from these structures, showed that the photoproducts were consistent with the previously assigned Hula-twist (HT) product, an unstable high energy conformer of the parent system. The absence of a significant deuterium isotope effect on rates of photochemical reaction appears to rule out the involvement of a hydrogen-tunnelling mechanism for the HT process. | en |
dc.source | Molecular Physics | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-33645790018&doi=10.1080%2f00268970500417747&partnerID=40&md5=fcebc8c1e7ca913f4dcc4b386810d3cf | |
dc.subject | Styrene | en |
dc.subject | Derivatives | en |
dc.subject | Infrared spectroscopy | en |
dc.subject | Conformations | en |
dc.subject | Photochemical reactions | en |
dc.subject | Isotopes | en |
dc.subject | Isomerization | en |
dc.subject | Energy conformer | en |
dc.subject | Hydrogen-tunnelling | en |
dc.subject | Photoisomerization | en |
dc.subject | Styrene derivative | en |
dc.title | Hula-twist photoisomerization of a styrene derivative examined by argon-matrix-infrared-spectroscopic method | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1080/00268970500417747 | |
dc.description.volume | 104 | |
dc.description.issue | 5-7 | |
dc.description.startingpage | 1009 | |
dc.description.endingpage | 1015 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :2</p> | en |
dc.source.abbreviation | Mol.Phys. | en |