dc.contributor.author | Nastopoulos, Vassilios | en |
dc.contributor.author | Kounavi, Konstantina A. | en |
dc.contributor.author | Manos, Manolis J. | en |
dc.contributor.author | Tasiopoulos, Anastasios J. | en |
dc.contributor.author | Perlepes, Spyros P. | en |
dc.creator | Nastopoulos, Vassilios | en |
dc.creator | Kounavi, Konstantina A. | en |
dc.creator | Manos, Manolis J. | en |
dc.creator | Tasiopoulos, Anastasios J. | en |
dc.creator | Perlepes, Spyros P. | en |
dc.date.accessioned | 2019-11-21T06:21:40Z | |
dc.date.available | 2019-11-21T06:21:40Z | |
dc.date.issued | 2010 | |
dc.identifier.issn | 1565-3633 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55889 | |
dc.description.abstract | Two new complexes, [Zn (O2CPh)2 (L)2] · 2MeOH (1 · 2MeOH) and [Ni2(O2CPh)) 4(L)2] · 2MeCN (2 · 2MeCN), have been synthesized and characterized by X-ray analysis in the course of an ongoing investigation of the MII/X-/L[MII =Co,Ni,Cu,Zn | en |
dc.description.abstract | X- = Cl-, Br-, I-, NCS-, NO3 -, N3 -, PhCO2- | en |
dc.description.abstract | L = 1 -methyl-4,5-diphenylimidazole] reaction system, aiming at understanding and assessing the relative strength and the way in which the intermolecular interactions control the supramolecular organization of these compounds. In the mononuclear complex 1 · 2MeOH, the benzoate ion acts as a monodentate ligand resulting in a distorted tetrahedral N2O 2coordination environment. Complex 2 · 2MeCN exhibits a dinuclear paddle-wheel structure | en |
dc.description.abstract | each NiII has a square pyramidal NiNO4 chromophore with four benzoate oxygens in the basal plane and the pyridine-type nitrogen atom of one ligand L at the apex. The structure of 1 · 2MeOH is stabilized by intramolecular - interactions between aromatic rings of adjacent 4,5-diphenylimidazole moieties | en |
dc.description.abstract | it is a feature also evidenced in similar compounds of the type [MX2L2]. Copyright © 2010 Konstantina A. Kounavi et al. | en |
dc.source | Bioinorganic Chemistry and Applications | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-77956785178&doi=10.1155%2f2010%2f178034&partnerID=40&md5=1a9da2f2e83eacf970078fcb55771356 | |
dc.title | Zinc(II) and nickel(II) benzoate complexes from the use of 1-methyl-4,5-diphenylimidazole | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1155/2010/178034 | |
dc.description.volume | 2010 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :4</p> | en |
dc.source.abbreviation | Bioinorg.Chem.Appl. | en |
dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
dc.contributor.orcid | Nastopoulos, Vassilios [0000-0003-4190-1342] | |
dc.gnosis.orcid | 0000-0002-4804-3822 | |
dc.gnosis.orcid | 0000-0003-4190-1342 | |