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dc.contributor.authorNastopoulos, Vassiliosen
dc.contributor.authorKounavi, Konstantina A.en
dc.contributor.authorManos, Manolis J.en
dc.contributor.authorTasiopoulos, Anastasios J.en
dc.contributor.authorPerlepes, Spyros P.en
dc.creatorNastopoulos, Vassiliosen
dc.creatorKounavi, Konstantina A.en
dc.creatorManos, Manolis J.en
dc.creatorTasiopoulos, Anastasios J.en
dc.creatorPerlepes, Spyros P.en
dc.description.abstractTwo new complexes, [Zn (O2CPh)2 (L)2] · 2MeOH (1 · 2MeOH) and [Ni2(O2CPh)) 4(L)2] · 2MeCN (2 · 2MeCN), have been synthesized and characterized by X-ray analysis in the course of an ongoing investigation of the MII/X-/L[MII =Co,Ni,Cu,Znen
dc.description.abstractX- = Cl-, Br-, I-, NCS-, NO3 -, N3 -, PhCO2-en
dc.description.abstractL = 1 -methyl-4,5-diphenylimidazole] reaction system, aiming at understanding and assessing the relative strength and the way in which the intermolecular interactions control the supramolecular organization of these compounds. In the mononuclear complex 1 · 2MeOH, the benzoate ion acts as a monodentate ligand resulting in a distorted tetrahedral N2O 2coordination environment. Complex 2 · 2MeCN exhibits a dinuclear paddle-wheel structureen
dc.description.abstracteach NiII has a square pyramidal NiNO4 chromophore with four benzoate oxygens in the basal plane and the pyridine-type nitrogen atom of one ligand L at the apex. The structure of 1 · 2MeOH is stabilized by intramolecular - interactions between aromatic rings of adjacent 4,5-diphenylimidazole moietiesen
dc.description.abstractit is a feature also evidenced in similar compounds of the type [MX2L2]. Copyright © 2010 Konstantina A. Kounavi et al.en
dc.sourceBioinorganic Chemistry and Applicationsen
dc.titleZinc(II) and nickel(II) benzoate complexes from the use of 1-methyl-4,5-diphenylimidazoleen
dc.description.volume2010 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied SciencesΤμήμα Χημείας / Department of Chemistry
dc.description.notes<p>Cited By :4</p>en
dc.contributor.orcidTasiopoulos, Anastasios J. [0000-0002-4804-3822]
dc.contributor.orcidNastopoulos, Vassilios [0000-0003-4190-1342]

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