dc.contributor.author | Passadis, Stamatis S. | en |
dc.contributor.author | Tsiafoulis, Constantinos G. | en |
dc.contributor.author | Drouza, Chryssoula | en |
dc.contributor.author | Tsipis, Athanassios C. | en |
dc.contributor.author | Miras, Haralampos N. | en |
dc.contributor.author | Keramidas, Anastasios D. | en |
dc.contributor.author | Kabanos, Themistoklis A. | en |
dc.creator | Passadis, Stamatis S. | en |
dc.creator | Tsiafoulis, Constantinos G. | en |
dc.creator | Drouza, Chryssoula | en |
dc.creator | Tsipis, Athanassios C. | en |
dc.creator | Miras, Haralampos N. | en |
dc.creator | Keramidas, Anastasios D. | en |
dc.creator | Kabanos, Themistoklis A. | en |
dc.date.accessioned | 2019-11-21T06:22:05Z | |
dc.date.available | 2019-11-21T06:22:05Z | |
dc.date.issued | 2016 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55978 | |
dc.description.abstract | Reaction of the oxidovanadium(IV)-LN-N species (LN-N is bipy = 2,2′-bipyridine or bipy-like molecules) with either BF4- or HF and/or KF results in the formation of compounds of the general formula cis-[VIV(=O)(F)(LN-N)2]+. Structural and spectroscopic (electron paramagnetic resonance) characterization shows that these compounds are in the tetravalent oxidation state containing a terminal fluorido ligand. Density functional theory calculations reveal that the VIV-F bond is mainly electrostatic, which is reinforced by reactivity studies that demonstrate the nucleophilicity of the fluoride ligand in a halogen exchange reaction and in fluorination of various organic substrates. © 2016 American Chemical Society. | en |
dc.source | Inorganic chemistry | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84958739811&doi=10.1021%2facs.inorgchem.5b02895&partnerID=40&md5=fab3c244269c167758a28c9a94c02d39 | |
dc.title | Synthesis, Bonding, and Reactivity of Vanadium(IV) Oxido-Fluorido Compounds with Neutral Chelate Ligands of the General Formula cis-[VIV(=O)(F)(LN-N)2]+ | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1021/acs.inorgchem.5b02895 | |
dc.description.volume | 55 | |
dc.description.issue | 4 | |
dc.description.startingpage | 1364 | |
dc.description.endingpage | 1366 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :2</p> | en |
dc.source.abbreviation | Inorg.Chem. | en |
dc.contributor.orcid | Keramidas, Anastasios D. [0000-0002-0446-8220] | |
dc.contributor.orcid | Drouza, Chryssoula [0000-0002-2630-4323] | |
dc.contributor.orcid | Kabanos, Themistoklis A. [0000-0001-6944-5153] | |
dc.contributor.orcid | Miras, Haralampos N. [0000-0002-0086-5173] | |
dc.gnosis.orcid | 0000-0002-0446-8220 | |
dc.gnosis.orcid | 0000-0002-2630-4323 | |
dc.gnosis.orcid | 0000-0001-6944-5153 | |
dc.gnosis.orcid | 0000-0002-0086-5173 | |