Investigating the photochemical dynamics of chlorine dioxide in water and acetonitrile using ultrafast pump-probe spectroscopy
AuthorPhilpott, M. J.
Hayes, Sophia C.
Reid, P. J.
SourceSpringer Series in Chemical Physics
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The photochemical reaction dynamics of chlorine dioxide (OClO) are investigated using femtosecond pump-probe spectroscopy. It is found that the majority of the dynamics can be attributed to the formation and vibrational relaxation of OClO from geminate recombination of the primary ClO and O photofragments.