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The role of oxygen and hydroxyl support species on the mechanism of H 2 production in the steam reforming of phenol over metal oxide-supported-Rh and -Fe catalysts

dc.contributor.authorPolychronopoulou, Kyriakien
dc.contributor.authorCosta, Costas N.en
dc.contributor.authorEfstathiou, Angelos M.en
dc.contributor.editorCortes Corberan V.en
dc.contributor.editorM. Millet J.M.en
dc.contributor.editorXenophon Verykios P.en
dc.creatorPolychronopoulou, Kyriakien
dc.creatorCosta, Costas N.en
dc.creatorEfstathiou, Angelos M.en
dc.date.accessioned2019-11-21T06:22:25Z
dc.date.available2019-11-21T06:22:25Z
dc.date.issued2006
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/56044
dc.description.abstractThe aim of this work was to probe for the first time the back-spillover of labile O and OH species during steam reforming of phenol towards H2 production over Rh and Fe supported on MgO, Mg-Ce-O and Mg-Ce-Zr-O metal oxides. This was made possible through SSITKA and other transient isotopic experiments (use of D2O and 18O2). The size of the active pool of H-containing species (H and/or OH) present under reaction conditions as a function of reaction T and catalyst composition, and deuterium kinetic isotope effects were measured. © 2005 Elsevier B.V. All rights reserved.en
dc.sourceProceedings of the First Conference of the European Union Coordination Action CO-ordination of Nanostructured Catalytic Oxidesen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-32544435441&doi=10.1016%2fj.cattod.2005.11.037&partnerID=40&md5=af2a0f0d46e10aba7c8f6581b3740db0
dc.subjectReaction kineticsen
dc.subjectOxygenen
dc.subjectCompositionen
dc.subjectCatalyst activityen
dc.subjectRhodiumen
dc.subjectAromatic compoundsen
dc.subjectIsotopesen
dc.subjectHydrogen productionen
dc.subjectSteam reformingen
dc.subjectSSITKAen
dc.subjectPhenolen
dc.subjectKinetic isotope effecten
dc.subjectOH spilloveren
dc.subjectOxygen spilloveren
dc.titleThe role of oxygen and hydroxyl support species on the mechanism of H 2 production in the steam reforming of phenol over metal oxide-supported-Rh and -Fe catalystsen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1016/j.cattod.2005.11.037
dc.description.volume112
dc.description.issue1-4
dc.description.startingpage89
dc.description.endingpage93
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Conference code: 66637en
dc.description.notesCited By :40</p>en
dc.source.abbreviationCatal Todayen
dc.contributor.orcidEfstathiou, Angelos M. [0000-0001-8393-8800]
dc.contributor.orcidPolychronopoulou, Kyriaki [0000-0002-0723-9941]
dc.contributor.orcidCosta, Costas N. [0000-0002-8459-0356]
dc.gnosis.orcid0000-0001-8393-8800
dc.gnosis.orcid0000-0002-0723-9941
dc.gnosis.orcid0000-0002-8459-0356


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