One-pot regioselective synthesis and X-ray crystal structure of a stable [60]fullerene trisadduct with the eedge,eface,trans-1 addition pattern
Date
2011ISSN
1359-7345Source
Chemical CommunicationsVolume
47Issue
43Pages
11948-11950Google Scholar check
Keyword(s):
Metadata
Show full item recordAbstract
The Bingel functionalisation of C60 with a structurally novel tether equipped with three reactive malonate groups afforded a C 2v-symmetrical eedge,eface,trans-1 trisadduct in a complete regioselective manner and in an excellent yield of 65%. The [60]fullerene trisadduct showed pronounced ability to crystallise and gave X-ray quality single crystals for analysis. © 2011 The Royal Society of Chemistry.