Show simple item record

Preparation of Blatter Radicals via Aza-Wittig Chemistry: The Reaction of N-Aryliminophosphoranes with 1-(Het)aroyl-2-aryldiazenes

dc.contributor.authorSavva, Anastasia C.en
dc.contributor.authorMirallai, Styliana I.en
dc.contributor.authorZissimou, Georgia A.en
dc.contributor.authorBerezin, Andrey A.en
dc.contributor.authorDemetriades, Marinaen
dc.contributor.authorKourtellaris, Andreasen
dc.contributor.authorConstantinides, Christos P.en
dc.contributor.authorNicolaides, C.en
dc.contributor.authorTrypiniotis, Theodossisen
dc.contributor.authorKoutentis, Panayiotis Andreasen
dc.creatorSavva, Anastasia C.en
dc.creatorMirallai, Styliana I.en
dc.creatorZissimou, Georgia A.en
dc.creatorBerezin, Andrey A.en
dc.creatorDemetriades, Marinaen
dc.creatorKourtellaris, Andreasen
dc.creatorConstantinides, Christos P.en
dc.creatorNicolaides, C.en
dc.creatorTrypiniotis, Theodossisen
dc.creatorKoutentis, Panayiotis Andreasen
dc.date.accessioned2019-11-21T06:22:42Z
dc.date.available2019-11-21T06:22:42Z
dc.date.issued2017
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/56104
dc.description.abstractReacting N-aryliminophosphoranes with 1-(het)aroyl-2-aryldiazenes in preheated diphenyl ether at ca. 150-250 °C for 5-25 min affords in most cases the 1,3-diaryl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yls (aka Blatter radicals) in moderate to good yields. All new compounds are fully characterized, including EPR and CV studies for the radicals. Single-crystal X-ray structures of 1-benzoyl-2-(perfluorophenyl)diazene and 1-(perfluorophenyl)-3-phenyl-1,4-dihydrobenzo[e][1,2,4]triazinyl are also presented. © 2017 American Chemical Society.en
dc.sourceJournal of Organic Chemistryen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85025144427&doi=10.1021%2facs.joc.7b01297&partnerID=40&md5=47b46fffe046b7fefbe3882c2aacf8b0
dc.subjectChemistryen
dc.subjectOrganic compoundsen
dc.subjectSingle crystal x-ray structuresen
dc.subjectDiphenyl etheren
dc.subjectDiazenesen
dc.titlePreparation of Blatter Radicals via Aza-Wittig Chemistry: The Reaction of N-Aryliminophosphoranes with 1-(Het)aroyl-2-aryldiazenesen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1021/acs.joc.7b01297
dc.description.volume82
dc.description.issue14
dc.description.startingpage7564
dc.description.endingpage7575
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.source.abbreviationJ.Org.Chem.en
dc.contributor.orcidKoutentis, Panayiotis Andreas [0000-0002-4652-7567]
dc.contributor.orcidConstantinides, Christos P. [0000-0001-6364-1102]
dc.contributor.orcidZissimou, Georgia A. [0000-0003-4821-9469]
dc.contributor.orcidMirallai, Styliana I. [0000-0002-8195-8741]
dc.gnosis.orcid0000-0002-4652-7567
dc.gnosis.orcid0000-0001-6364-1102
dc.gnosis.orcid0000-0003-4821-9469
dc.gnosis.orcid0000-0002-8195-8741


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record