Connectivity Effects in Isomeric Naphthalenedinitrenes
Ημερομηνία
2001Συγγραφέας
Serwinski, P. R.Walton, R.
Sanborn, J. A.
Lahti, P. M.
Enyo, T.
Miura, D.
Tomioka, H.
Nicolaïdes, Andrew N.
ISSN
1523-7060Source
Organic lettersVolume
3Issue
3Pages
357-360Google Scholar check
Metadata
Εμφάνιση πλήρους εγγραφήςΕπιτομή
(Matrix Presented) UV-vis, FTIR, and ESR spectroscopic studies were carried out on samples of 1,4- and 1,5-naphthalenediazide that were photolyzed at cryogenic temperatures in argon and frozen solvent matrices. Mononitrenes and diiminediyl systems are produced. Spectral and computational results are consistent with quinonoidal singlet ground-state structures for the diiminediyls, rather than aromatic dinitrene structures.