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Synthesis, experimental and theoretical investigation of a new type nickel dithiolene complex

dc.contributor.authorSoras, Georgiosen
dc.contributor.authorPsaroudakis, Nikolasen
dc.contributor.authorManos, Manolis J.en
dc.contributor.authorTasiopoulos, Anastasios J.en
dc.contributor.authorLiakos, D. G.en
dc.contributor.authorMousdis, Georgios A.en
dc.creatorSoras, Georgiosen
dc.creatorPsaroudakis, Nikolasen
dc.creatorManos, Manolis J.en
dc.creatorTasiopoulos, Anastasios J.en
dc.creatorLiakos, D. G.en
dc.creatorMousdis, Georgios A.en
dc.date.accessioned2019-11-21T06:22:48Z
dc.date.available2019-11-21T06:22:48Z
dc.date.issued2013
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/56126
dc.description.abstractA new nickel complex with an extended multisulfur dithiolene ligand, [Ni(dmeodddt)2] (dmeodddt = 5,6-dimethoxy-5,6-dihydro-1,4-dithiine-2, 3-dithiolate), has been synthesized and characterized by IR, Raman, UV-Vis and NMR spectroscopy. Its crystal structure has been determined by X-ray crystallography, showing that the Ni atom is tetra-coordinated and has a square planar geometry with the methoxy groups placed above and below the metal dithiolene core, due to stereochemical hindrance. Electrochemical measurements showed that the complex exhibits four 1e reversible redox waves. The results of theoretical calculations showed a good agreement with the experimental findings and gave answers about its electronic structure. © 2013 Elsevier Ltd. All rights reserved.en
dc.sourcePolyhedronen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84885107664&doi=10.1016%2fj.poly.2013.06.033&partnerID=40&md5=39e9e4f03995b651935a8d5b9dfe6798
dc.subjectCrystal structureen
dc.subjectIR and Raman spectraen
dc.subjectCyclic voltammetryen
dc.subjectDFT calculationsen
dc.subjectDithiolene complexesen
dc.subjectUV-Vis-NIR spectraen
dc.titleSynthesis, experimental and theoretical investigation of a new type nickel dithiolene complexen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1016/j.poly.2013.06.033
dc.description.volume62
dc.description.startingpage208
dc.description.endingpage217
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :4</p>en
dc.source.abbreviationPolyhedronen
dc.contributor.orcidTasiopoulos, Anastasios J. [0000-0002-4804-3822]
dc.gnosis.orcid0000-0002-4804-3822


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