dc.contributor.author | Spanopoulos, Ioannis | en |
dc.contributor.author | Bratsos, Ioannis | en |
dc.contributor.author | Tampaxis, Christos | en |
dc.contributor.author | Kourtellaris, Andreas | en |
dc.contributor.author | Tasiopoulos, Anastasios J. | en |
dc.contributor.author | Charalambopoulou, Georgia Ch | en |
dc.contributor.author | Steriotis, Theodore A. | en |
dc.contributor.author | Trikalitis, Pantelis N. | en |
dc.creator | Spanopoulos, Ioannis | en |
dc.creator | Bratsos, Ioannis | en |
dc.creator | Tampaxis, Christos | en |
dc.creator | Kourtellaris, Andreas | en |
dc.creator | Tasiopoulos, Anastasios J. | en |
dc.creator | Charalambopoulou, Georgia Ch | en |
dc.creator | Steriotis, Theodore A. | en |
dc.creator | Trikalitis, Pantelis N. | en |
dc.date.accessioned | 2019-11-21T06:22:49Z | |
dc.date.available | 2019-11-21T06:22:49Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 1466-8033 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/56130 | |
dc.description.abstract | The direct solvothermal reaction of Mg(NO3)2·6H2O in dimethylformamide at 130 °C leads to the formation of highly crystalline α-[Mg3(O2CH)6] with an expanded unit cell. Successful pore activation was performed after heating the material at 240 °C under dynamic vacuum. In contrast to literature reports, the pores in the activated solid are accessible to nitrogen molecules and the corresponding BET surface area is 496 m2 g-1, very close to the geometric area calculated from the single crystal structure. A detailed gas-sorption study (N2, Ar, H2, CO2, CH4 and NH3) is reported. The material is ammonia stable showing a reversible uptake of 5.4 mmol g-1 at 298 K, while the corresponding CO2 uptake is 2.2 mmol g-1 with moderate CO2/CH4 (4.6) selectivity but high CO2/N2 (23) and CH4/N2 (5.2) selectivity. The latter is among the highest values reported to date in the entire family of porous materials. The H2 uptake at 77 K is 1.2 wt% which is the highest among the reported values for various magnesium formates. © The Royal Society of Chemistry 2015. | en |
dc.source | CrystEngComm | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84919684216&doi=10.1039%2fc4ce01667j&partnerID=40&md5=0899b25527e0a15a90b47a56cbf7e3f4 | |
dc.title | Enhanced gas-sorption properties of a high surface area, ultramicroporous magnesium formate | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1039/c4ce01667j | |
dc.description.volume | 17 | |
dc.description.issue | 3 | |
dc.description.startingpage | 532 | |
dc.description.endingpage | 539 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :8</p> | en |
dc.source.abbreviation | Crystengcomm | en |
dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
dc.contributor.orcid | Trikalitis, Pantelis N. [0000-0002-6286-2955] | |
dc.gnosis.orcid | 0000-0002-4804-3822 | |
dc.gnosis.orcid | 0000-0002-6286-2955 | |