| dc.contributor.author | Stamatatos, Theocharis C. | en |
| dc.contributor.author | Perlepes, Spyros P. | en |
| dc.contributor.author | Manos, Manolis J. | en |
| dc.contributor.author | Tasiopoulos, Anastasios J. | en |
| dc.contributor.author | Klouras, N. | en |
| dc.creator | Stamatatos, Theocharis C. | en |
| dc.creator | Perlepes, Spyros P. | en |
| dc.creator | Manos, Manolis J. | en |
| dc.creator | Tasiopoulos, Anastasios J. | en |
| dc.creator | Klouras, N. | en |
| dc.date.accessioned | 2019-11-21T06:22:50Z | |
| dc.date.available | 2019-11-21T06:22:50Z | |
| dc.date.issued | 2011 | |
| dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/56134 | |
| dc.description.abstract | A convenient route has been developed for the formation of [Ti IV3O(OMe)6(σ5-C 5H5)3](I3) (2) involving methanolysis (and possibly hydrolysis) of species derived from titanocene diiodide, [TiIV(σ5-C5H5) 2I2] (1), under aerobic conditions. Single-crystal X-ray crystallography reveals that the cation of 2 consists of three TiIV's in a triangular arrangement bridged by a central 3-oxide | en |
| dc.description.abstract | the latter lies 0.686A ° out of the Ti3 plane. Each edge of the triangle is bridged by oxygen of σ1 :μ-MeO. Terminal ligation is provided by three methoxide and three cyclopentadienyl groups. All TiIV centers are five-coordinate in an extremely distorted geometry. IR and electronic data are discussed in terms of the known structure and coordination modes of O 2, MeO, and σ5-C5Hσ5 . A proposal for the mechanism of the unexpected formation of the triiodide (I3) counteranion that is present in the crystal structure of 2 is also provided. © 2011 Taylor & Francis. | en |
| dc.source | Journal of Coordination Chemistry | en |
| dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-79960509340&doi=10.1080%2f00958972.2011.597850&partnerID=40&md5=2dfe1d25b9c418a4bf69e66bd702e482 | |
| dc.subject | Bis(σ | el |
| dc.subject | Crystal structures | en |
| dc.subject | 5-cyclopentadienyl)diiodotitanium(IV) | en |
| dc.subject | Methanolysis route | en |
| dc.subject | Reactivity studies | en |
| dc.subject | Triangular titanium(IV) complexes | en |
| dc.subject | Tris(cyclopentadienyl)hexamethoxido-oxidotrititanium(IV) triiodide | en |
| dc.title | Unexpected formation, X-ray structure, and characterization of the triangular [Ti3O(OMe)6(σ5-C 5H5)3](I3) complex from hydrolysis and methanolysis of [Ti(σ5-C5H5) 2I2] | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.identifier.doi | 10.1080/00958972.2011.597850 | |
| dc.description.volume | 64 | |
| dc.description.issue | 13 | |
| dc.description.startingpage | 2377 | |
| dc.description.endingpage | 2387 | |
| dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
| dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
| dc.type.uhtype | Article | en |
| dc.description.notes | <p>Cited By :3</p> | en |
| dc.source.abbreviation | J.Coord.Chem. | en |
| dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
| dc.contributor.orcid | Stamatatos, Theocharis C. [0000-0002-9798-9331] | |
| dc.gnosis.orcid | 0000-0002-4804-3822 | |
| dc.gnosis.orcid | 0000-0002-9798-9331 | |
