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Multi-compartment unimolecular micelles from (ABC)n multi-arm star triblock terpolymers

dc.contributor.authorStavrouli, N.en
dc.contributor.authorTriftaridou, Aggeliki I.en
dc.contributor.authorPatrickios, Costas S.en
dc.contributor.authorTsitsilianis, C.en
dc.creatorStavrouli, N.en
dc.creatorTriftaridou, Aggeliki I.en
dc.creatorPatrickios, Costas S.en
dc.creatorTsitsilianis, C.en
dc.date.accessioned2019-11-21T06:22:59Z
dc.date.available2019-11-21T06:22:59Z
dc.date.issued2007
dc.identifier.issn1022-1336
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/56162
dc.description.abstractFour linear and four star equimolar terpolymers based on non-ionic hydrophilic methoxy hexa(ethylene glycol) methacrylate, ionizable hydrophilic 2-(dimethylamino)ethyl methacrylate and neutral hydrophobic methyl methacrylate were synthesized using group transfer polymerization and investigated in aqueous dilute solutions. It was found that the (ABC)n multi-arm star terpolymers formed unimolecular micelles comprising three centrosymmetric compartments. The position of each compartment could be determined by the block sequence (ABC, ACB or BAC) atwill. On the other hand, the ABC linear counterparts formed loose associates with very low aggregation numbers. It was shown that the polymer architecture (linear versus star) greatly affected the micellization phenomena of the terpolymers in selective media. © 2007 WILEY-VCH Verlag GmbH & Co. KCaA.en
dc.sourceMacromolecular Rapid Communicationsen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-34447513596&doi=10.1002%2fmarc.200600738&partnerID=40&md5=564ddaed45bacbf8d45b765abba4820c
dc.subjectAgglomerationen
dc.subjectSynthesis (chemical)en
dc.subjectMicellesen
dc.subject2-(dimethylamino)ethyl methacrylateen
dc.subjectBlock copolymersen
dc.subjectHydrophobicityen
dc.subjectSolutionsen
dc.subjectTerpolymersen
dc.subjectAmphiphilic polymersen
dc.subjectABC star terpolymersen
dc.subjectBlock sequencesen
dc.subjectCentrosymmetric compartmentsen
dc.subjectMethoxy hexa(ethylene glycol) methacrylateen
dc.subjectMulticompartment unimolecular micellesen
dc.subjectStar equimolar terpolymersen
dc.titleMulti-compartment unimolecular micelles from (ABC)n multi-arm star triblock terpolymersen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1002/marc.200600738
dc.description.volume28
dc.description.issue5
dc.description.startingpage560
dc.description.endingpage566
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :26</p>en
dc.source.abbreviationMacromol.Rapid Commun.en
dc.contributor.orcidPatrickios, Costas S. [0000-0001-8855-0370]
dc.gnosis.orcid0000-0001-8855-0370


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