Rare oxidation-state combinations and unusual structural motifs in hexanuclear Mn complexes using 2-pyridyloximate ligands
Date
2010Author
Stoumpos, Constantinos C.
Inglis, R.
Roubeau, O.
Sartzi, H.
Kitos, Alexandros A.
Milios, Constantinos J.
Aromí, Guillem
Tasiopoulos, Anastasios J.
Nastopoulos, Vassilios
Brechin, E. K.
Perlepes, Spyros P.
Source
Inorganic chemistryVolume
49Issue
10Pages
4388-4390Google Scholar check
Metadata
Show full item recordAbstract
The use of phenyl-2-pyridyl ketone oxime and di-2-pyridyl ketone oxime in Mn chemistry has led to hexanuclear clusters with unprecedented (Mn II4MnIIIMnIV) or extremely rare (MnIIMnIII5 and MnII 3MnIII3) metal oxidation-state combinations and uncommon structural motifs. © 2010 American Chemical Society.