dc.contributor.author | Tasiopoulos, Anastasios J. | en |
dc.contributor.author | Harden, N. C. | en |
dc.contributor.author | Abboud, K. A. | en |
dc.contributor.author | Christou, George | en |
dc.creator | Tasiopoulos, Anastasios J. | en |
dc.creator | Harden, N. C. | en |
dc.creator | Abboud, K. A. | en |
dc.creator | Christou, George | en |
dc.date.accessioned | 2019-11-21T06:23:06Z | |
dc.date.available | 2019-11-21T06:23:06Z | |
dc.date.issued | 2003 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/56189 | |
dc.description.abstract | The preparation and crystal structures of three polymeric Mn compounds are reported. The comproportionation reaction between Mn(OAc)2·4H2O and KMnO4 in MeOH-AcOH (2:3) leads to isolation of {[Mn(OH)(OAc)2]·AcOH·H2O}n (1). The structure consists of chains of [Mn(μ-OH)(μ-OAc)2Mn] triply-bridged units. The chains are linked into 3D networks by hydrogen-bonding interactions involving the AcOH and H2O molecules of crystallization. Oxidation of [Mn12O12(O2CPh)16 (H2O)4] by controlled potential electrolysis in CH2Cl2 with NBu2nPF6 as supporting electrolyte yields a brown solution which slowly turns purple and then pale yellow. Deep purple crystals, obtained by addition of hexanes, were identified crystallographically as {(NBu4n])[Mn2(O2 PF2)6]·2/3CH2 Cl2}n (2), which is mixed-valent and consists of a chain of [MnII(μ-O2PF2)3 MnIII] triply-bridged units. Bond distances, bond valence sum calculations, and a Jahn-Teller (JT) axial elongation at the MnIII sites confirm a trapped-valence situation. Dissolution of Mn(OAc)2·4H2O in EtOH results in a subsequent crystallization of a white solid analyzing as [Mn(OAc)2·3/8H2O] (3a). Crystals grown from MeOH-Et2O were structurally identified as [Mn4(OAc)8(MeOH)2]n (3b), and consist of Y-shaped Mn4 units bridged by AcO- groups to give a 3D network. Variable-temperature, solid-state magnetic susceptibility studies establish that 1, 3a and 3b are antiferromagnetically coupled to give diamagnetic ground states. © 2002 Elsevier Science Ltd. All rights reserved. | en |
dc.source | Polyhedron | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0038573732&doi=10.1016%2fS0277-5387%2802%2901262-7&partnerID=40&md5=94bf95a224a915621ece2455f7e3bddc | |
dc.subject | article | en |
dc.subject | cluster analysis | en |
dc.subject | molecular interaction | en |
dc.subject | crystal structure | en |
dc.subject | crystallization | en |
dc.subject | structure analysis | en |
dc.subject | polymer | en |
dc.subject | polymerization | en |
dc.subject | manganese | en |
dc.subject | oxidation | en |
dc.subject | Crystal structures | en |
dc.subject | crystallography | en |
dc.subject | electrolysis | en |
dc.subject | Mn compounds | en |
dc.subject | Polymeric | en |
dc.subject | Solid state | en |
dc.title | Preparation and crystal structures of MnII, mixed-valent MnII/MnIII, and MnIII polymeric compounds | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1016/S0277-5387(02)01262-7 | |
dc.description.volume | 22 | |
dc.description.issue | 1 | |
dc.description.startingpage | 133 | |
dc.description.endingpage | 143 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :30</p> | en |
dc.source.abbreviation | Polyhedron | en |
dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
dc.gnosis.orcid | 0000-0002-4804-3822 | |