dc.contributor.author | Tasiopoulos, Anastasios J. | en |
dc.contributor.author | Wernsdorfer, W. | en |
dc.contributor.author | Abboud, K. A. | en |
dc.contributor.author | Christou, George | en |
dc.creator | Tasiopoulos, Anastasios J. | en |
dc.creator | Wernsdorfer, W. | en |
dc.creator | Abboud, K. A. | en |
dc.creator | Christou, George | en |
dc.date.accessioned | 2019-11-21T06:23:10Z | |
dc.date.available | 2019-11-21T06:23:10Z | |
dc.date.issued | 2005 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/56201 | |
dc.description.abstract | We describe a new synthetic procedure in Mn cluster chemistry involving reductive aggregation of permanganate (MnO4-) ions in MeOH/benzoic acid solution and the first two products that were obtained from this procedure. The first one is the anion [Mn12O12(OMe)2(O 2CPh)16(H2O)2]2- which was isolated as a black microcrystalline material when the solution was left at room temperature overnight. The microcrystalline material was recrystallized from CH2Cl2/hexanes and gave the above mentioned anion as a mixture of two crystal forms (NnBu4)2[Mn 12O12(OMe)2(O2CPh) 16(H2O)2]·2H2O· 4CH2Cl2 and (NnBu4) 2[Mn12O12(OMe)2(O 2CPh)16(H2O)2]·2H 2O·CH2Cl2. The anion contains a central [MnIV4(μ3-O)2(μ-O)2(μ-OMe)2]6+unit surrounded by a non-planar ring of eight MnIII atoms that are connected to the central Mn4 unit by eight bridging μ3-O2- ions. This anion is remarkably similar to the well known [Mn12O12(O 2CR)16(H2O)4] complexes (hereafter called "normal [Mn12]"), with the main difference being the structure of the central cores. The second compound was the polymeric [Mn(OMe)(O2CPh)2]n that was obtained when the solution was left at room temperature for ∼2 weeks. The compound contains a linear chain of repeating [MnIII(μ-O2CPh) 2(μ-OMe)MnIII] units. The chains are parallel to each other and are interacting weakly through π-stacking between the benzoate rings of different chains. Variable temperature ac magnetic measurements and hysteresis studies revealed that both anions are SMMs and like normal [Mn 12] clusters, display both faster- and slower-relaxing magnetization dynamics that we assign to the presence of JT isomerism. Variable temperature magnetic susceptibility studies establish that the MnIII centers of the polymer are antiferromagnetically coupled resulting in a diamagnetic ground state. © 2005 Elsevier Ltd. All rights reserved. | en |
dc.source | Polyhedron | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-27644460595&doi=10.1016%2fj.poly.2005.03.074&partnerID=40&md5=5cd6e80a1da1b164d7ffbcf99485e3d4 | |
dc.subject | Magnetic properties | en |
dc.subject | Single-molecule magnet | en |
dc.subject | Permanganate | en |
dc.subject | Reductive aggregation | en |
dc.title | Two isomeric [Mn12O12(OMe)2(O 2CPh)16(H2O)2]2- single-molecule magnets and a MnIII polymer prepared by a reductive aggregation synthetic route | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1016/j.poly.2005.03.074 | |
dc.description.volume | 24 | |
dc.description.issue | 16-17 | |
dc.description.startingpage | 2505 | |
dc.description.endingpage | 2512 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :9</p> | en |
dc.source.abbreviation | Polyhedron | en |
dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
dc.gnosis.orcid | 0000-0002-4804-3822 | |