dc.contributor.author | Theocharis, Charis R. | en |
dc.creator | Theocharis, Charis R. | en |
dc.date.accessioned | 2019-11-21T06:23:13Z | |
dc.date.available | 2019-11-21T06:23:13Z | |
dc.date.issued | 1992 | |
dc.identifier.issn | 1058-725X | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/56215 | |
dc.description.abstract | In this paper the effect of fluoro substitution on the packing of the 2-benzyl-5-benzylidene- and 2,5-dibenzylidenecyclopentanone frameworks will be discussed. We chose the fluoro substituent because it has a much smaller van der Waals radius than other substituents used hitherto, while it is very similar to that of hydrogen. This allows a method to distinguish between substituent effects due to size and those due to non-bonded interactions on the crystal packing. It can be shown that intermolecular atom-atom interactions involving the fluoro groups hold sway over the effect of the volume of the subtituents upon crystal packing. A comparison is made between the F…F contacts in these structures and others published in the literature. © 1992, Taylor & Francis Group, LLC. All rights reserved. | en |
dc.source | Molecular Crystals and Liquid Crystals Science and Technology.Section A.Molecular Crystals and Liquid Crystals | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947672387&doi=10.1080%2f10587259208025808&partnerID=40&md5=baa40fa735482c6d89aca0d439497031 | |
dc.subject | cambridge structural database | en |
dc.subject | crystal packing | en |
dc.subject | fluorine-fluorine interactions | en |
dc.subject | fluorobenzenes | en |
dc.subject | solid state photocycloaddition | en |
dc.subject | substituent effects | en |
dc.title | Fluoro substitution effects in the crystal packing of fluorobenzenes | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1080/10587259208025808 | |
dc.description.volume | 211 | |
dc.description.issue | 1 | |
dc.description.startingpage | 89 | |
dc.description.endingpage | 97 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.source.abbreviation | Mol Cryst Liq Cryst Sci Technol Sect A Mol Crys Liq Cryst | en |
dc.contributor.orcid | Theocharis, Charis R. [0000-0002-1669-4954] | |
dc.gnosis.orcid | 0000-0002-1669-4954 | |