Study of the crystal and molecular structure of the 9-cyanoanthracene trans dimer and of its monomerisation
Date
1985Source
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed PhasesVolume
81Issue
4Pages
857-874Google Scholar check
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The structure of the 9-cyanoanthracene trans dimer (9-CNAD) has been solved by direct methods [P1, a = 10.146(1) Å, b = 17.785(1) Å, c = 11.501(1) Å, α = 92.95(1)°, β = 95.59(1)°, γ = 89.82(1)°, Z = 4]. No evidence for X-ray-induced monomerisation was observed, although a 20% fading of the crystal occurred during data collection. On heating a 9-CNAD crystal to 420 K, a yellow single crystal (9-CNADY) was obtained. Its crystal structure [P1, a = 10.217(2) Å, b = 10.235(2) Å, c = 11.594(2) Å, α = 95.20(2)°, β = 90.37(2)°, γ = 120.13(1)°, Z = 2] was solved to show that the sample was still dimeric to an extent of 92%. This single-crystal → single-crystal transition is topotactic, and monomerisation occurs homogeneously. Further heating leads to a complete, heterogeneous and topotactic monomerisation. The monomeric component in 9-CNADY was not located. Final R was 0.0436 for 9-CNAD and 0.1015 for 9-CNADY.