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The formation of ClOO following the photoexcitation of aqueous OClO studied by two-color, time-resolved resonance Raman spectroscopy

dc.contributor.authorThomsen, C. L.en
dc.contributor.authorPhilpott, M. P.en
dc.contributor.authorHayes, Sophia C.en
dc.contributor.authorReid, P. J.en
dc.creatorThomsen, C. L.en
dc.creatorPhilpott, M. P.en
dc.creatorHayes, Sophia C.en
dc.creatorReid, P. J.en
dc.date.accessioned2019-11-21T06:23:18Z
dc.date.available2019-11-21T06:23:18Z
dc.date.issued2000
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/56238
dc.description.abstractThe photochemistry of chlorine dioxide (OClO) is investigated by two-color time-resolved resonance Raman spectroscopy. Pump and probe wavelengths of 390 and 260 nm, respectively, are used to monitor photoproduct formation following aqueous OClO photoexcitation. Depletion and subsequent recovery of the OClO scattering intensities is observed consistent with subpicosecond reformation of OClO via geminate recombination of the primary photoproducts. Intensity is observed at 1442 cm-1 consistent with ClOO formation that appears and decays with time constants of 27.9 ± 4.5 ps and 398 ± 50ps, respectively. The results presented here represent the first direct evidence for ClOO formation following the photoexcitation of aqueous OClO. © 2000 American Institute of Physics.en
dc.sourceJournal of Chemical Physicsen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-0003175706&partnerID=40&md5=d1e807a373b49aacd68b2dfd44798d2f
dc.titleThe formation of ClOO following the photoexcitation of aqueous OClO studied by two-color, time-resolved resonance Raman spectroscopyen
dc.typeinfo:eu-repo/semantics/article
dc.description.volume112
dc.description.issue2
dc.description.startingpage505
dc.description.endingpage508
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :34</p>en
dc.source.abbreviationJ.Chem.Phys.en
dc.contributor.orcidHayes, Sophia C. [0000-0002-2809-6193]
dc.gnosis.orcid0000-0002-2809-6193


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