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The structure of the hyponitrite species in a heme Fe-Cu binuclear center

dc.contributor.authorVarotsis, Constantinosen
dc.contributor.authorOhta, T.en
dc.contributor.authorKitagawa, T.en
dc.contributor.authorSoulimane, T.en
dc.contributor.authorPinakoulaki, Eftychiaen
dc.creatorVarotsis, Constantinosen
dc.creatorOhta, T.en
dc.creatorKitagawa, T.en
dc.creatorSoulimane, T.en
dc.creatorPinakoulaki, Eftychiaen
dc.date.accessioned2019-11-21T06:23:29Z
dc.date.available2019-11-21T06:23:29Z
dc.date.issued2007
dc.identifier.issn1433-7851
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/56275
dc.description.abstractNO laughing matter: The enzymatic production of laughing gas (N 2O) from two molecules of NO requires the formation of the N-N bond and the subsequent cleavage of the N-OH bond. Resonance Raman spectroscopic studies have now provided evidence for the formation of the key intermediate, the hyponitrite species (see the optimized molecular structure), in the heme a3 Fe-CuB binuclear center of ba3- oxidoreductase from Thermus thermophilus. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.en
dc.sourceAngewandte Chemie - International Editionen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-34250374882&doi=10.1002%2fanie.200602963&partnerID=40&md5=aca3b1ec4cd4c043cd6b87a23602c7dd
dc.subjectarticleen
dc.subjectunclassified drugen
dc.subjectchemistryen
dc.subjectNitric oxideen
dc.subjectReaction kineticsen
dc.subjectRaman spectroscopyen
dc.subjectchemical structureen
dc.subjectcopperen
dc.subjectOxidationen
dc.subjectMolecular Structureen
dc.subjectEnzymesen
dc.subjectironen
dc.subjectNitrogen oxidesen
dc.subjectChemical bondsen
dc.subjectRaman spectrometryen
dc.subjecthemeen
dc.subjectNitritesen
dc.subjectSpectrum Analysis, Ramanen
dc.subjectStructure elucidationen
dc.subjectThermus thermophilusen
dc.subjectnitriteen
dc.subjecthyponitriteen
dc.subjectHyponitrite speciesen
dc.subjectMetalloenzymesen
dc.titleThe structure of the hyponitrite species in a heme Fe-Cu binuclear centeren
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1002/anie.200602963
dc.description.volume46
dc.description.issue13
dc.description.startingpage2210
dc.description.endingpage2214
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :36</p>en
dc.source.abbreviationAngew.Chem.Int.Ed.en
dc.contributor.orcidPinakoulaki, Eftychia [0000-0003-3320-6112]
dc.contributor.orcidVarotsis, Constantinos [0000-0003-2771-8891]
dc.gnosis.orcid0000-0003-3320-6112
dc.gnosis.orcid0000-0003-2771-8891


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