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Addition of Electron-Rich Aromatics to Azafullerenium Carbocation. A Stepwise Electrophilic Substitution Mechanism

dc.contributor.authorVougioukalakis, G. C.en
dc.contributor.authorChronakis, Nikosen
dc.contributor.authorOrfanopoulos, Michaelen
dc.creatorVougioukalakis, G. C.en
dc.creatorChronakis, Nikosen
dc.creatorOrfanopoulos, Michaelen
dc.date.accessioned2019-11-21T06:23:31Z
dc.date.available2019-11-21T06:23:31Z
dc.date.issued2003
dc.identifier.issn1523-7060
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/56283
dc.description.abstract(Matrix presented) The reaction between the C59N+ carbocation and the electron-rich aromatic compounds toluene and anisole has been mechanistically studied. The measured intermolecular kinetic isotope effects are consistent with an electrophilic aromatic substitution mechanism in which the arenium cation is formed by electrophilic attack of C 59N+ on the aromatic ring in the first step of the reaction, followed by hydrogen abstraction in a rate-determining second step.en
dc.sourceOrganic lettersen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-0346753433&doi=10.1021%2fol0357604&partnerID=40&md5=6eddd674580ec6518a07a3feb3ef8cb9
dc.subjectarticleen
dc.subjectkineticsen
dc.subjectelectronen
dc.subjectchemical reactionen
dc.subjectmolecular dynamicsen
dc.subjectaromatic compounden
dc.subjectfullerene derivativeen
dc.subjecthydrogenen
dc.subjecttolueneen
dc.subjectanisoleen
dc.subjectcarbocationen
dc.titleAddition of Electron-Rich Aromatics to Azafullerenium Carbocation. A Stepwise Electrophilic Substitution Mechanismen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1021/ol0357604
dc.description.volume5
dc.description.issue24
dc.description.startingpage4603
dc.description.endingpage4606
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :18</p>en
dc.source.abbreviationOrg.Lett.en
dc.contributor.orcidChronakis, Nikos [0000-0002-2726-5290]
dc.contributor.orcidOrfanopoulos, Michael [0000-0002-7785-2071]
dc.contributor.orcidVougioukalakis, G. C. [0000-0002-4620-5859]
dc.gnosis.orcid0000-0002-2726-5290
dc.gnosis.orcid0000-0002-7785-2071
dc.gnosis.orcid0000-0002-4620-5859


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