dc.contributor.author | Wallace, P. M. | en |
dc.contributor.author | Bolinger, J. C. | en |
dc.contributor.author | Hayes, Sophia C. | en |
dc.contributor.author | Reid, P. J. | en |
dc.creator | Wallace, P. M. | en |
dc.creator | Bolinger, J. C. | en |
dc.creator | Hayes, Sophia C. | en |
dc.creator | Reid, P. J. | en |
dc.date.accessioned | 2019-11-21T06:23:32Z | |
dc.date.available | 2019-11-21T06:23:32Z | |
dc.date.issued | 2003 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/56285 | |
dc.description.abstract | The role of actinic wavelength in OClO photochemistry was explored using femtosecond pump-probe spectroscopy. Specifically, the evolution of optical density was monitored at probe wavelengths from 267 to 900 nm following 355-nm photoexcitation of OClO dissolved in water and acetonitrile. A central result was that the extent of geminate recombination in a given solvent is dependent on the interplay between the rate of excited-state vibrational relaxation versus the energy needed to overcome the energy barrier to dissociation. | en |
dc.source | Journal of Chemical Physics | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0037460259&doi=10.1063%2f1.1531613&partnerID=40&md5=99d30c5690ffb2d3d02c8731ceb6bbc2 | |
dc.subject | Quantum theory | en |
dc.subject | Chlorine compounds | en |
dc.subject | Water | en |
dc.subject | Solutions | en |
dc.subject | Dissolution | en |
dc.subject | Photolysis | en |
dc.subject | Density (optical) | en |
dc.subject | Acetonitrile | en |
dc.subject | Photoproducts | en |
dc.subject | Actinic wavelength | en |
dc.subject | Chlorine dioxide | en |
dc.subject | Photoexcitation | en |
dc.subject | Quantum yield | en |
dc.subject | Recombination efficiency | en |
dc.title | On the actinic wavelength dependence of OClO photochemistry in solution | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1063/1.1531613 | |
dc.description.volume | 118 | |
dc.description.issue | 4 | |
dc.description.startingpage | 1883 | |
dc.description.endingpage | 1890 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :5</p> | en |
dc.source.abbreviation | J.Chem.Phys. | en |
dc.contributor.orcid | Hayes, Sophia C. [0000-0002-2809-6193] | |
dc.gnosis.orcid | 0000-0002-2809-6193 | |