dc.contributor.author | Zissimou, Georgia A. | en |
dc.contributor.author | Kourtellaris, Andreas | en |
dc.contributor.author | Koutentis, Panayiotis A. | en |
dc.creator | Zissimou, Georgia A. | en |
dc.creator | Kourtellaris, Andreas | en |
dc.creator | Koutentis, Panayiotis A. | en |
dc.date.accessioned | 2021-01-25T09:44:46Z | |
dc.date.available | 2021-01-25T09:44:46Z | |
dc.date.issued | 2018 | |
dc.identifier.issn | 1523-7060 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/63020 | |
dc.description.abstract | Isodiphenylfluorindine (5) reacts with K2Cr2O7/H+ to give 13-oxoisodiphenylfluorindinium perchlorate (7) (75%), but with phenyliodine bis(trifluoroacetate) (PIFA) or MnO2 it gives the zwitterionic and quinoidal cruciform 13,13′-dimers 11 (85%) and 12 (89%), respectively. The zwitterionic 13,13′-dimer 11 can be rapidly converted with MnO2 into the quinoidal 13,13′-dimer 12 (100%). UV–vis, NMR, single-crystal X-ray diffraction, and density functional theory studies support the structural assignments of all products. The electrochemical behavior of the compounds is also presented. | en |
dc.source | Organic Letters | en |
dc.source.uri | https://doi.org/10.1021/acs.orglett.7b03998 | |
dc.title | Oxidation of Isodiphenylfluorindine: Routes to 13-Oxoisodiphenylfluorindinium Perchlorate and Fluorindine Cruciform Dimers | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1021/acs.orglett.7b03998 | |
dc.description.volume | 20 | |
dc.description.issue | 3 | |
dc.description.startingpage | 844 | |
dc.description.endingpage | 847 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.source.abbreviation | Org. Lett. | en |
dc.contributor.orcid | Zissimou, Georgia A. [0000-0003-4821-9469] | |
dc.contributor.orcid | Koutentis, Panayiotis A. [0000-0002-4652-7567] | |
dc.gnosis.orcid | 0000-0003-4821-9469 | |
dc.gnosis.orcid | 0000-0002-4652-7567 | |