dc.contributor.author | Nicolaou, Maria | en |
dc.contributor.author | Drouza, Chryssoula | en |
dc.contributor.author | Keramidas, Anastasios D. | en |
dc.creator | Nicolaou, Maria | en |
dc.creator | Drouza, Chryssoula | en |
dc.creator | Keramidas, Anastasios D. | en |
dc.date.accessioned | 2021-01-25T09:44:50Z | |
dc.date.available | 2021-01-25T09:44:50Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 1369-9261 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/63053 | |
dc.description.abstract | Three unique mixed-valence polyoxofluorovanadate clusters have been synthesized through a facile preparation process. The structure of these clusters is controlled by the addition of organic ligands. Single-crystal X-ray diffraction revealed that the clusters have the formula (XyH2)4[VV10VIV4O14(μ-O)10(μ3-O)10(μ3-F)2F4] (1), (Xy = m-xylylenediamine), (pyH)4(H)2[VV10VIV2O12(μ-O)8(μ3-O)10(μ3-F)2(pic)2] (2) and (pyH)4(H)3(Na+)[VV7VIV2O9(μ-O)8(μ3-O)4(μ5-F)(pic)4]2 (3), (py = pyridine, pic− = picolinate), with 2 and 3 representing the first examples of polyoxofluorovanadate clusters coordinated to a chelating ligand. The electron paramagnetic resonance (EPR) spectroscopy of 1 revealed that the spins of the VIV centers are coupled to each other, in contrast to the isolated spins of the isostructural [VV12VIV2O16(μ-O)10(μ3-O)10(μ3-F)2(L)2]6−, where L: im = imidazole (4) | en |
dc.description.abstract | py (5). The trigonal bipyramidal coordinated VV atoms of 1, 4 and 5 mimic the structure of the active site of the vanadium dependent peroxidases and 4 and 5 exhibit peroxidase like activity. | en |
dc.language.iso | en | en |
dc.source | New Journal of Chemistry | en |
dc.source.uri | https://pubs.rsc.org/en/content/articlelanding/2019/nj/c9nj01999e | |
dc.title | Controlled one pot synthesis of polyoxofluorovanadate molecular hybrids exhibiting peroxidase like activity | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1039/C9NJ01999E | |
dc.description.volume | 43 | |
dc.description.issue | 45 | |
dc.description.startingpage | 17595 | |
dc.description.endingpage | 17602 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.source.abbreviation | New J. Chem. | en |
dc.contributor.orcid | Keramidas, Anastasios D. [0000-0002-0446-8220] | |
dc.contributor.orcid | Drouza, Chryssoula [0000-0002-2630-4323] | |
dc.gnosis.orcid | 0000-0002-0446-8220 | |
dc.gnosis.orcid | 0000-0002-2630-4323 | |