Spin-Crossover Phenomenon in Microcrystals and Nanoparticles of a [Fe(2-mpz)2Ni(CN)4] Two-Dimensional Hofmann-Type Polymer: A Detailed Nano-Topographic Study
Date
2019Author
Polyzou, Christina D.Malina, Ondřej
Tuček, Jiri
Zbořil, Radek
Panagiotou, Nikos
Tasiopoulos, Anastasios J.
Boukos, Nikos
Parthenios, John
Kalarakis, Alexandros N.
Tangoulis, Vassilis
ISSN
0020-1669Source
Inorganic ChemistryVolume
58Issue
20Pages
13733-13736Google Scholar check
Metadata
Show full item recordAbstract
The diamagnetic two-dimensional Hofmann-type metal–organic framework [ZnII(2-mpz)2Ni(CN)4] has been successfully synthesized along with its isostructural hysteretic spin-crossover FeII analogue in the form of both bulk microcrystalline powder and nanoparticles. Detailed atomic force microscopy topographic study revealed a nanogrowth relationship between the height and length of the nanoparticle.