dc.contributor.author | Winterlich, Meghan | en |
dc.contributor.author | McHugh, Darragh | en |
dc.contributor.author | O'Toole, Evan | en |
dc.contributor.author | Skordi, Katerina | en |
dc.contributor.author | O'Malley, Ciaran | en |
dc.contributor.author | Sanii, Rana | en |
dc.contributor.author | Tasiopoulos, Anastasios J. | en |
dc.contributor.author | Erxleben, Andrea | en |
dc.contributor.author | Mayans, Júlia | en |
dc.contributor.author | Morrison, Liam | en |
dc.contributor.author | McArdle, Patrick | en |
dc.contributor.author | Zaworotko, Michael J. | en |
dc.contributor.author | Tylianakis, Emmanuel | en |
dc.contributor.author | Froudakis, George | en |
dc.contributor.author | Papatriantafyllopoulou, Constantina | en |
dc.creator | Winterlich, Meghan | en |
dc.creator | McHugh, Darragh | |
dc.creator | Tasiopoulos, Anastasios J. | |
dc.creator | Erxleben, Andrea | |
dc.creator | Mayans, Julia | |
dc.creator | Froudakis, George | |
dc.creator | Papatriantafyllopoulou, Constantina | |
dc.date.accessioned | 2024-09-02T06:53:15Z | |
dc.date.available | 2024-09-02T06:53:15Z | |
dc.date.issued | 2021-05-28 | |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/66352 | en |
dc.description.abstract | Metal organic frameworks (MOFs) have attracted considerable attention in recent years due to their use in a wide range of environmental, industrial and biomedical applications. The employment of benzophenone-4,4′-dicarboxylic acid (bphdcH2) in MOF chemistry provided access to the 3D mixed metal MOFs [CoNa2(bphdc)2(DMF)2]n (NUIG2) and [ZnK2(bphdc)2(DMF)2]n (NUIG3), and the 2D homometallic MOF [Co2(OH)(bphdcH)2(DMF)2(H2O)2]n(OH)·DMF (1·DMF). 1·DMF is based on a dinuclear SBU and consists of interpenetrating networks with an sql topology. Dc magnetic susceptibility studies were carried out in 1·DMF and revealed the presence of weak antiferomagnetic exchange interactions between the metal centres. NUIG2 and NUIG3 are structural analogues of [ZnNa2(bphdc)2(DMF)2]n (NUIG1), which has shown an exceptionally high encapsulation for ibuprophen (Ibu), NO and metal ions. Both NUIG2 and NUIG3 display high metal ion (CoII, NiII, CuII) adsorption capacity, comparable to that of NUIG1, with NUIG2 exhibiting good performance in Ibu uptake (780 mg Ibu per g NUIG2). Monte Carlo simulations were conducted in NUIG1 in order to assess its adsorption capacity for other guest molecules, and revealed that it possesses an outstanding CO2 uptake at ambient pressure, which is larger than that of the previously reported best functioning species (104 vs. 100 cm3 (stp) per cm3). Furthermore, NUIG1 exhibits high selectivity for CO2 over CH4. | en |
dc.language.iso | eng | en |
dc.publisher | Royal Society of Chemistry | en |
dc.source | Dalton Transactions | en |
dc.source.uri | https://pubs.rsc.org/en/content/articlelanding/2021/dt/d1dt00940k | en |
dc.title | Expanding the NUIG MOF family: synthesis and characterization of new MOFs for selective CO2adsorption, metal ion removal from aqueous systems, and drug delivery applications | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.uncontrolledterm | Mesh Adsorption | en |
dc.subject.uncontrolledterm | Carbon Dioxide | en |
dc.subject.uncontrolledterm | Metal-organic frameworks | en |
dc.subject.uncontrolledterm | Water engineering controlled terms carbon dioxide | en |
dc.subject.uncontrolledterm | Chemicals removal (water treatment) | en |
dc.subject.uncontrolledterm | Copper compounds | en |
dc.subject.uncontrolledterm | Magnetic susceptibility | en |
dc.subject.uncontrolledterm | Medical applications | en |
dc.subject.uncontrolledterm | Metal ions | en |
dc.subject.uncontrolledterm | Metal organic framework | en |
dc.subject.uncontrolledterm | Metals | en |
dc.subject.uncontrolledterm | Monte Carlo methods | en |
dc.subject.uncontrolledterm | Nickel compounds | en |
dc.subject.uncontrolledterm | Organometallics emtree drug terms corbon dioxide | en |
dc.subject.uncontrolledterm | Metal organic framework | en |
dc.subject.uncontrolledterm | Water engineering uncontrolled terms adsorption capacities | en |
dc.subject.uncontrolledterm | Biomedical applications | en |
dc.subject.uncontrolledterm | DC magnetic susceptibility | en |
dc.subject.uncontrolledterm | Drug delivery applications | en |
dc.subject.uncontrolledterm | Metal Ion removal | en |
dc.subject.uncontrolledterm | Metalorganic frameworks (MOFs) | en |
dc.subject.uncontrolledterm | Structural analogue | en |
dc.subject.uncontrolledterm | Synthesis and characterizations emtree medical terms adsorption | en |
dc.subject.uncontrolledterm | Chemistry engineering main heading drug delivery | en |
dc.identifier.doi | 10.1039/d1dt00940k | |
dc.description.volume | 50 | |
dc.description.issue | 20 | |
dc.description.startingpage | 6997 | |
dc.description.endingpage | 7006 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | © 2021 The Royal Society of Chemistry. | en |
dc.contributor.orcid | Winterlich, Meghan [0000-0003-0681-9212] | |
dc.contributor.orcid | McHugh, Darragh [0000-0002-0081-1781] | |
dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
dc.contributor.orcid | Erxleben, Andrea [0000-0002-7309-8972] | |
dc.contributor.orcid | Mayans, Julia [0000-0001-8875-8075] | |
dc.contributor.orcid | Froudakis, George [0000-0002-6907-1822] | |
dc.contributor.orcid | Papatriantafyllopoulou, Constantina [0000-0002-5652-7747] | |
dc.type.subtype | SCIENTIFIC_JOURNAL | en |
dc.gnosis.orcid | 0000-0003-0681-9212 | |
dc.gnosis.orcid | 0000-0002-0081-1781 | |
dc.gnosis.orcid | 0000-0002-4804-3822 | |
dc.gnosis.orcid | 0000-0002-7309-8972 | |
dc.gnosis.orcid | 0000-0001-8875-8075 | |
dc.gnosis.orcid | 0000-0002-6907-1822 | |
dc.gnosis.orcid | 0000-0002-5652-7747 | |