Browsing by Subject "Electrochemistry"

Article

Computational predictions of the tensile properties of electrospun fibre meshes: Effect of fibre diameter and fibre orientation

Barocas, V. Η; Stylianopoulos, T.; Bashur, C. A.; Goldstein, A. S.; Guelcher, S. A. (2008)

The mechanical properties of biomaterial scaffolds are crucial for their efficacy in tissue engineering and regenerative medicine. At the microscopic scale, the scaffold must be sufficiently rigid to support cell adhesion, ...

Article

Design and synthesis of aromatic molecules for probing electric fields at the nanoscale

Faez, Sanli; Verhart, Nico R.; Markoulides, Marios Savva; Buda, Francesco; Gourdon, André; Orrit, Michel (2015)

Article

Donor atom electrochemical contribution to redox potentials of square pyramidal vanadyl complexes

Vlasiou, Manolis; Drouza, Chryssoula; Kabanos, Themistoklis A.; Keramidas, Anastasios D. (2015)

A simple donor atom additivity relationship has been used to calculate the donor atom electrochemical contribution (DEC) of the Oac (acetylacetonate-enolic oxygen), OPh (phenolic oxygen), SPh (mercaptophenol sulfur), Nam ...

Article

Fabrication of nanorods by metal evaporation inside the pores of ultra-thin porous alumina templates

Kokonou, M.; Rebholz, Claus; Giannakopoulos, K. P.; Doumanidis, C. C. (2007)

Porous alumina has attracted a great deal of attention as a template material for the growth of nanowires and nanodots. Typically, the pores have a high aspect ratio, which forbids the use of evaporation techniques for ...

Article

Identifying potential candidates for donor-acceptor copolymers on a series of 4H-1,2,6-thiadiazines: An electrochemical approach

Economopoulos, Solon P.; Koutentis, Panayiotis Andreas; Ioannidou, Heraklidia A.; Choulis, Stelios A. (2013)

A series of synthesized small organic molecules based on the 4H-1,2,6-thiadiazine moiety are studied using electrochemistry, to probe their potential as comonomer building blocks for solar-absorbing polymers for organic ...

Article

Investigation of the stability of polyelectrolyte multilayer coatings in open-tubular capillary electrochromatography using laser scanning confocal microscopy

Kapnissi‐Christodoulou, Constantina P.; Lowry, M.; Agbaria, R. A.; Geng, L.; Warner, I. M. (2005)

A simple polyelectrolyte multilayer (PEM) coating procedure was used for the development of stable modified capillaries. PEM coatings were constructed in fused-silica capillaries using alternating rinses of cationic and ...

Article

Model investigations for vanadium-protein interactions: Vanadium(III) compounds with dipeptides and their oxovanadium(IV) analogues

Tasiopoulos, Anastasios J.; Tolis, Evangelos I.; Tsangaris, John Michael; Evangelou, Angelos M.; Woollins, J. D.; Slawin, A. M. Z.; Pessoa, J. C.; Correia, I.; Kabanos, Themistoklis A. (2002)

The reaction of VCl3 with 1,10-phenanthroline and a series of dipeptides (H2dip), having aliphatic as well as aromatic side chains, in methyl alcohol and in the presence of triethylamine affords vanadium(III) compounds of ...

Article

Oxovanadium(IV)-sulfite compounds: Synthesis and structural and physical studies

Chilas, G. I.; Miras, Haralampos N.; Manos, Manolis J.; Woollins, J. D.; Slawin, A. M. Z.; Stylianou, Marios; Keramidas, Anastasios D.; Kabanos, Themistoklis A. (2005)

Reaction of VIVOCl2 in strongly acidic aqueous solution with either (NH4)2SO3 or Na 2SO3 and Bu4NBr at ∼70 °C in the pH range 2.5-4.5 gives the clusters (NH4)2{[V 4IV)(μ4-O)2(μ3-OH) 2](VIVO)2(μ3-SO3) 4O4(H2O)2} and (n-Bu ...

Article

The preparation and characterization of 5-substituted-4-chloro-1,2,3- dithiazolium salts and their conversion into 4-substituted-3-chloro-1,2,5- thiadiazoles

Koutentis, Panayiotis Andreas (2005)

A series of monosubstituted acetonitriles were treated with disulfur dichloride at room temperature in CH2Cl2 to afford 5-substituted-4-chloro-1,2,3-dithiazolium chlorides 1. Where the 5-substituent was not a good leaving ...

Article

Synthesis and aqueous solution properties of multinuclear oxo-bridged vanadium(IV/V) complexes

Drouza, Chryssoula; Keramidas, Anastasios D. (2000)

Reaction of the multifunctional phenolic ligands 2,5-bis[N,N-bis(carboxymethyl)aminomethyl]hydroquinone (H6cahq), 2,2'-bis[N,N-bis(carboxymethyl)aminomethyl]-4,4'-isopropylidenedi phenol (H6capd), 2,2',2''-tris[N,N-bis(c ...

Article

Synthesis, characterization of dinuclear vanadium(III) hydroquinonate- iminodiacetate complexes

Drouza, Chryssoula; Vlasiou, Manolis; Keramidas, Anastasios D. (2014)

A new VIII complex (1) of 2,5-bis[N,N-bis(carboxymethyl) aminomethyl]hydroquinone (bicah6-) was synthesized by reaction of H6bicah with two equivalents of VCl3 and six equivalents of base in aqueous solution. Crystallographic ...

Article

Unexpected reduction of vanadium(IV) to vanadium(III) in the presence of the chelate ligands 2,2′-bipyridine (bpy) and 1,8-hydroxyquinoline (Hquin)

Manos, Manolis J.; Tasiopoulos, Anastasios J.; Raptopoulou, Catherine P.; Terzis, Aris; Derek Woollins, J.; Slawin, A. M. Z.; Keramidas, Anastasios D.; Kabanos, Themistoklis A. (2001)

The structures, NMR spectra and electrochemical properties of the vanadium(III) compounds, cis-[VIIICl2-(acac)(bpy)] and [VIII(quin)3]·2CH3OH, formed from [VIVCl2(acac)2]·0.25CH2Cl 2 (Hacac = pentane-2,4-dione) and ...

Doctoral Thesis Open Access

Αξιολόγηση της συνεργειακής δράσης ιοντικών υγρών και άλλων προσθέτων για την ανάπτυξη μεθόδων διαχωρισμού με την τεχνική της ηλεκτροφόρησης τριχοειδούς

Μαυρουδή, Μαρία Χ. (Πανεπιστήμιο Κύπρου, Σχολή Θετικών και Εφαρμοσμένων Επιστημών / University of Cyprus, Faculty of Pure and Applied Sciences, 2015-12)

Η ανάπτυξη και η αξιολόγηση της συνεργιστικής δράσης ιοντικών υγρών (ILs) και άλλων πρόσθετων για διαχωρισμούς στην ηλεκτροφόρηση τριχοειδούς (CE) αποτελεί το ερευνητικό αντικείμενο της παρούσας διδακτορικής διατριβής. Η ...