Browsing Τμήμα Χημείας / Department of Chemistry by Author "Aromí, Guillem"
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"Depolymerization" approach in Mn cluster chemistry: Controlled cleavage of a 1D coordination polymer consisting of Mn8 units in its constituent, discrete Mn8 complex
Stoumpos, Constantinos C.; Roubeau, O.; Aromí, Guillem; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Escuer, Albert; Perlepes, Spyros P. (2010)The cleavage of a 1D coordination polymer (MnII 2MnIII6)n containing recognizable octanuclear units to obtain the discrete MnIIMnIII6 cluster is reported. © 2009 American Chemical Society.
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Article
Rare oxidation-state combinations and unusual structural motifs in hexanuclear Mn complexes using 2-pyridyloximate ligands
Stoumpos, Constantinos C.; Inglis, R.; Roubeau, O.; Sartzi, H.; Kitos, Alexandros A.; Milios, Constantinos J.; Aromí, Guillem; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Brechin, E. K.; Perlepes, Spyros P. (2010)The use of phenyl-2-pyridyl ketone oxime and di-2-pyridyl ketone oxime in Mn chemistry has led to hexanuclear clusters with unprecedented (Mn II4MnIIIMnIV) or extremely rare (MnIIMnIII5 and MnII 3MnIII3) metal oxidation-state ...
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Article
Use of the sulfato ligand in 3d-metal cluster chemistry: A family of hexanuclear nickel(II) complexes with 2-pyridyl-substituted oxime ligands
Papatriantafyllopoulou, Constantina; Aromí, Guillem; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Raptopoulou, Catherine P.; Teat, S. J.; Escuer, Albert; Perlepes, Spyros P. (2007)The initial use of 2-pyridyl-substituted oximes [(py)C(R)-NOH