Browsing Τμήμα Χημείας / Department of Chemistry by Author "Manos, Manolis J."
Now showing items 1-20 of 57
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A 1-D coordination polymer based on a Mn40 octagonal super-structure
Manoli, Maria; Inglis, R.; Manos, Manolis J.; Papaefstathìou, Giannis S.; Brechin, E. K.; Tasiopoulos, Anastasios J. (2013)A 1-D coordination polymer, constructed using a combination of diols and phenolic oximes, contains a novel [Mn9] sub-unit, a nanosized [Mn40] octagonal super-structure and a [Mn21] repeating unit. © 2013 The Royal Society ...
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Approaches to molecular magnetic materials from the use of cyanate groups in higher oxidation state metal cluster chemistry: Mn14 and Mn 16
Alexandropoulos, Dimitris I.; Papatriantafyllopoulou, Constantina; Li, C. -L; Cunha-Silva, L.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Wernsdorfer, W.; Christou, George; Stamatatos, Theocharis C. (2013)The initial employment of cyanato groups in higher oxidation state manganese cluster chemistry, in conjunction with the gem-diolate form of di-2-pyridylketone or 2,6-diacetylpyridine dioxime chelate ligands, has afforded ...
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Assessment of organotins against the linoleic acid, glutathione and CT-DNA
Banti, Christina N.; Gkaniatsou, E. I.; Kourkoumelis, Nikolaos; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Bakas, Thomas V.; Hadjikakou, Sotiris K. (2014)The already known di-n-butyltin(IV) complex of the chiral anti-inflammatory drug naproxen (Hnapr) of formula [(n-Bu-)2Sn(nap)2] (1), was re-synthesized here with an alternative method and it was used for the assessment of ...
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ChemInform Abstract: One‐Step Conversion of 2‐Amino‐N′‐arylbenzamidines into 3‐Aryl‐4‐imino‐3,4‐dihydroquinazoline‐2‐carbonitriles Using 4,5‐Dichloro‐1,2,3‐dithiazolium Chloride.
Mirallai, Styliana I.; Manos, Manolis J.; Koutentis, Panayiotis Andreas (2014)
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Copper(I)/(II) or silver(I) ions towards 2-mercaptopyrimidine: An exploration of a chemical variability with possible biological implication
Batsala, G. K.; Dokorou, Vaso N.; Kourkoumelis, Nikolaos; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Mavromoustakos, Thomas M.; Simčič, M.; Golič-Grdadolnik, S.; Hadjikakou, Sotiris K. (2012)Direct reaction of copper(I) chloride with 2-mercaptopyrimidine (pmtH) in the presence of the triphenylphosphine (tpp) in 1:1:2 M ratio forms the mixed ligand Cu(I) complex with formula [CuCl(tpp) 2(pmtH)] (1). The dimeric ...
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Discrete and encapsulated molecular grids: Homometallic Mn15 and heterometallic Mn24Ni2 aggregates
Charalambous, Maria; Zartilas, Sotiris M.; Moushi, Eleni E.; Papatriantafyllopoulou, Constantina; Manos, Manolis J.; Stamatatos, Theocharis C.; Mukherjee, S.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2014)Two molecular grid-like clusters are reported, one is a discrete [3 × 5] grid and the other a [3 × 4] grid within a Mn12Ni 2 loop. Both Mn24Ni2 and Mn15 aggregates display novel and aesthetically pleasing structures with ...
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Erratum: Reinvestigating the Reaction of 1H-Pyrazol-5-amines with 4,5-Dichloro-1,2,3-dithiazolium Chloride: A Route to Pyrazolo[3,4-c]isothiazoles and Pyrazolo[3,4-d]thiazoles (Journal of Organic Chemistry (2014) 79 (4025-4037) DOI: 10.1021/jo500509e)
Koyioni, Maria G.; Manoli, Maria; Manos, Manolis J.; Koutentis, Panayiotis Andreas (2015)
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A flexible Cd2+ metal organic framework with a unique (3,3,6)-connected topology, unprecedented secondary building units and single crystal to single crystal solvent exchange properties
Kyprianidou, Eleni J.; Papaefstathìou, Giannis S.; Manos, Manolis J.; Tasiopoulos, Anastasios J. (2012)A new flexible Cd2+ metal organic framework (MOF), denoted as UCY-3, which is the second example of a MOF with the ligand H3CIP [H3CIP = 5-(4-carboxybenzylideneamino)isophthalic acid], is reported. It shows a unique ...
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Flexible lanthanide MOFs as highly selective and reusable liquid MeOH sorbents
Efthymiou, Constantinos G.; Kyprianidou, Eleni J.; Milios, Constantinos J.; Manos, Manolis J.; Tasiopoulos, Anastasios J. (2013)A series of new 3-D Ln3+ metal-organic frameworks (MOFs), which are based on the semi-rigid ligand H3CIP [H3CIP = 5-(4-carboxybenzylideneamino)isophthalic acid], [Ln2(CIP) 2(DMF)4-x(H2O)x] (Ln3+ = La3+, Ce3+, Pr3+, Sm3+, ...
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Heterometallic FeIII-CeIV complexes from the use of aliphatic aminoalcohol ligands
Kizas, Christos M.; Papatriantafyllopoulou, Constantina; Manos, Manolis J.; Tasiopoulos, Anastasios J. (2013)Six novel heteronuclear FeIII/CeIV clusters with the ligands 3-amino-1-propanol (Hap) and 2-(hydroxymethyl)piperidine (Hhmpip) [FeIII4CeIV6O8(L) 4((CH3)3CCO2)12(RCO 2)4] (R = CH3, L = ap-, 1
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Hexanuclear complexes from the use of a series of amino-alcohol ligands in Fe chemistry
Papatriantafyllopoulou, Constantina; Kizas, Christos M.; Manos, Manolis J.; Boudalis, Athanassios K.; Sanakis, Yiannis; Tasiopoulos, Anastasios J. (2013)Eight novel FeIII6 clusters with the amino-alcohol ligands 3-amino-1-propanol (apH), N-hydroxyethylpiperidine (N-hepipH), 2-hydroxyethylpiperidine (2-hepipH), 2-aminobenzylalcohol (2-abzaH), N-hydroxyethylmorpholine ...
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A highly porous interpenetrated metal-organic framework from the use of a novel nanosized organic linker
Manos, Manolis J.; Markoulides, Marios Savva; Malliakas, C. D.; Papaefstathìou, Giannis S.; Chronakis, Nikos; Kanatzidis, M. G.; Trikalitis, Pantelis N.; Tasiopoulos, Anastasios J. (2011)The initial use of a novel elongated tricarboxylic acid H3hmpib in metal-organic framework (MOF) chemistry resulted in a [Zn4O(hmpib) 2] MOF (UCY-1) with pyrite topology. The compound displays a remarkably high internal ...
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Insertion of functional groups into a Nd 3+ metal-organic framework via single-crystal-to-single-crystal coordinating solvent exchange
Manos, Manolis J.; Kyprianidou, Eleni J.; Papaefstathìou, Giannis S.; Tasiopoulos, Anastasios J. (2012)Single-crystal-to-single-crystal (SCSC) transformations represent some of the most fascinating phenomena in chemistry. They are not only intriguing from a basic science point of view but also provide a means to modify or ...
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Interaction of antimony(III) chloride with thiourea, 2-mercapto-5-methyl- benzimidazole, 3-methyl-2-mercaptobenzothiazole, 2-mercaptopyrimidine, and 2-mercaptopyridine
Ozturk, I. I.; Kourkoumelis, Nikolaos; Hadjikakou, Sotiris K.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Butler, I. S.; Balzarini, J.; Hadjiliadis, Nick (2011)New antimony(III) chloride complexes with heterocyclic thioamides, thiourea (TU), 2-mercapto- 5-methyl-benzimidazole (MMBZIM), 3-methyl-2- mercaptobenzothiazole (MMBZT), 2-mercaptopyrimidine (PMT), 2-mercaptopyridine (PYT) ...
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Interesting copper(ii)-assisted transformations of 2-acetylpyridine and 2-benzoylpyridine
Kitos, Alexandros A.; Efthymiou, Constantinos G.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Escuer, Albert; Perlepes, Spyros P. (2016)The reactions of various copper(ii) sources with 2-acetylpyridine, (py)(me)CO, and 2-benzoylpyridine, (py)(ph)CO, under strongly basic conditions have been studied and novel ligand transformations have been discovered. ...
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Interesting copper(ii)-assisted transformations of 2-acetylpyridine and 2-benzoylpyridine1
Kitos, Alexandros A.; Efthymiou, Constantinos G.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Escuer, Albert; Perlepes, Spyros P. (2015)
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A microporous Co2+ metal organic framework with single-crystal to single-crystal transformation properties and high CO2 uptake
Moushi, Eleni E.; Kourtellaris, Andreas; Spanopoulos, Ioannis; Manos, Manolis J.; Papaefstathìou, Giannis S.; Trikalitis, Pantelis N.; Tasiopoulos, Anastasios J. (2015)The synthesis and characterization of {[Co9(INA)18(H2O)6]·11DMF·15H2O}∞ (Co9-INA·11DMF·15H2O) (INA- = the anion of isonicotinic acid) is reported. It exhibits a rigid 3D-porous structure with a Co9 repeating unit consisting ...
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A [Mn32] double-decker wheel
Manoli, Maria; Inglis, R.; Manos, Manolis J.; Nastopoulos, Vassilios; Wernsdorfer, W.; Brechin, E. K.; Tasiopoulos, Anastasios J. (2011)Inventing the double wheel: A mixed-valent [Mn32] cluster with a very rare "double-decker" wheel topology (see its metal-oxygen core: MnIII blue, MnII pink, O red) is reported. It is by far the highest-nuclearity example ...
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Monomeric compounds containing the cis-[V(=O)(OH)]+ core
Tolis, Evangelos I.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Raptopoulou, Catherine P.; Terzis, Aris; Sigalas, Michael P.; Deligiannakis, Yiannis G.; Kabanos, Themistoklis A. (2002)HYSCORE with a vanadium core: Examples of monomeric metal compounds containing the cis-[M(=O)(OH)]n+ unit, namely the VIVO2+ complexes [VIVO(OH)(bipy)2]BF4 (1
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A new class of ferromagnetically-coupled mixed valence vanadium(IV/V) polyoxometalates
Manos, Manolis J.; Tasiopoulos, Anastasios J.; Tolis, Evangelos I.; Lalioti, N.; Woollins, J. D.; Slawin, A. M. Z.; Sigalas, Michael P.; Kabanos, Themistoklis A. (2003)Reaction of [VVIOCl2(thf)2] with a bidentate nitrogen-donor ligand (L: phen = 1,10-phenanthroline, 5-mephen = 5-methyl-1,10-phenanthroline, bipy = 2,2′-bipyridine, 5,5′-me2bipy = 5,5′-dimethyl-2,2′-bipy) in methyl alcohol, ...