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Synthesis of Enantiopure T-Symmetrical [6:0]-Hexakis Adducts of C60 Equipped with 1,2-Glycol Substituted cyclo-Monomalonate Addends
(2016)
The synthesis of T-symmetrical [6:0]-hexakis adducts of C60 bearing enantiopure cyclo-monomalonate addends equipped with 1,2-glycol groups masked as isopropylidene acetals is presented. The deprotection of the acetals ...
Discovery of anti-cancer activity for benzo[1,2,4]triazin-7-ones: Very strong correlation to pleurotin and thioredoxin reductase inhibition
(2016)
The thioredoxin (Trx)–thioredoxin reductase (TrxR) system plays a key role in maintaining the cellular redox balance with Trx being over-expressed in a number of cancers. Inhibition of TrxR is an important strategy for ...
Radioactivity and metal concentrations in marine sediments associated with mining activities in Ierissos Gulf, North Aegean Sea, Greece
(2016)
Marine sediment samples were collected from Ierissos Gulf, N Aegean Sea, close to the coastal mining facilities. Measurements of radionuclide and metal concentrations, mineral composition and grain size distribution were ...
Synthesis and photophysical studies of a low-symmetry tribenzoisothiazoloporphyrazine
(2016)
A new low-symmetry tetraazaporphyrin has been synthesized and characterized by 1H NMR, electronic spectroscopies and high resolution mass spectrometry. The photophysical behavior of the newly synthesized low-symmetry zinc ...
N2O decomposition over ceria-promoted Ir/Al2O3 catalysts: The role of ceria
(2016)
The impact of CeO2 in the Al2O3-20wt% CeO2 support prepared by the co-precipitation method on the Ir particle size, morphology and oxidation state, and in turn on the deN2O catalytic activity (1000ppmN2O) of supported Ir ...
Filling the gap between the quantum and classical worlds of nanoscale magnetism: Giant molecular aggregates based on paramagnetic 3d metal ions
(2016)
In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and 3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term "giant clusters" is used herein to denote ...