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Structural motifs and biological studies of new antimony(iii) iodide complexes with thiones
(2010)
Eight new antimony(III) iodide complexes of the heterocyclic thioamides, 2-mercapto-1-methylimidazole (MMI), 2-mercaptobenzlmidazole (MBZIM), 5-ethoxy-2-mercaptobenzimldazole (EtMBZIM), 2-mercaptothiazolidine (MTZD), ...
Synthesis, characterization and biological activity of antimony(III) or bismuth(III) chloride complexes with dithiocarbamate ligands derived from thiuram degradation
(2014)
Antimony(III) or bismuth(III) complexes of formulae {[SbCl(Me 2DTC)2]n} (1), {[BiCl(Me2DTC) 2]n} (2) and {[Bi(Et2DTC)3] 2} (3) (Me2DTCH = dimethyldithiocarbamate, C 3H7NS2 and Et2DTCH = diethyldithiocarbamate, C5H11NS2) ...
A single-chain magnet based on linear [MnIII2MnII] units
(2014)
The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [MnIII2MnII] repeating unit are described. It displays single-chain magnet (SCM) behaviour with ...
One-pot thermally chemocontrolled double Diels-Alder strategies. A route to [4 + 2] functionalisation/[4 + 2] derivatization of C60
(2013)
The one-pot double Diels-Alder reactions of 3,4-di(methylene) tetrahydrothiophene-1,1-dioxide using temperature as the only chemocontrol element are described. Zn-dust promoted the 1,4-debromination of 3,4-bis(bromomethy ...
Zinc(II) and nickel(II) benzoate complexes from the use of 1-methyl-4,5-diphenylimidazole
(2010)
Two new complexes, [Zn (O2CPh)2 (L)2] · 2MeOH (1 · 2MeOH) and [Ni2(O2CPh)) 4(L)2] · 2MeCN (2 · 2MeCN), have been synthesized and characterized by X-ray analysis in the course of an ongoing investigation of the MII/X-/L[MII ...
Study on single crystal structure of the antimony(III) bromide complex with 3-methyl-2-mercaptobenzothiazole and biological activity of some antimony(III) bromide complexes with thioamides
(2012)
Crystals of the [SbBr3(MMBZT)2] (1) complex (MMBZT = N-methyl-2- mercaptobenzothiazole) were grown from acetonitrile/methanol of the filtrate derived from the reaction between 3-methyl-2-mercaptobenzo thiazole (MMBZT) in ...
Interaction of antimony(III) chloride with thiourea, 2-mercapto-5-methyl- benzimidazole, 3-methyl-2-mercaptobenzothiazole, 2-mercaptopyrimidine, and 2-mercaptopyridine
(2011)
New antimony(III) chloride complexes with heterocyclic thioamides, thiourea (TU), 2-mercapto- 5-methyl-benzimidazole (MMBZIM), 3-methyl-2- mercaptobenzothiazole (MMBZT), 2-mercaptopyrimidine (PMT), 2-mercaptopyridine (PYT) ...
Synthesis and structural characterization of new cu(I) complexes with the antithyroid drug 6-n-propyl-thiouracil. Study of the cu(I)-catalyzed intermolecular cycloaddition of iodonium ylides toward benzo[b]furans with pharmaceutical implementations
(2012)
The reaction of copper(I) iodide with 6-n-propylthiouracil (ptu) in the presence or absence of the triphenylphosphine (tpp) or tri(p-tolyl)phosphine (tptp) in a 1:1:2 molar ratio forms the mixed ligand Cu(I) complex with ...
Quantitative preparation of 3,4-di(methylene)tetrahydrothiophene-1,1- dioxide by Zn-induced 1,4-debromination. A valuable 6-C reactive diene in [4+2] cycloadditions with DMAD and [60]fullerene
(2012)
Optimum reaction conditions for the quantitative preparation of the highly reactive 3,4-di(methylene)tetrahydrothiophene-1,1-dioxide are described. The method involves the zinc-induced 1,4-debromination of 3,4-bis(bromom ...
Hexanuclear complexes from the use of a series of amino-alcohol ligands in Fe chemistry
(2013)
Eight novel FeIII6 clusters with the amino-alcohol ligands 3-amino-1-propanol (apH), N-hydroxyethylpiperidine (N-hepipH), 2-hydroxyethylpiperidine (2-hepipH), 2-aminobenzylalcohol (2-abzaH), N-hydroxyethylmorpholine ...