A single-chain magnet based on linear [MnIII2MnII] units
Date
2014Author
Papatriantafyllopoulou, Constantina
Zartilas, Sotiris M.
Manos, Manolis J.
Pichon, C.
Tasiopoulos, Anastasios J.
Clérac, R.
ISSN
1359-7345Source
Chemical CommunicationsVolume
50Issue
94Pages
14873-14876Google Scholar check
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Show full item recordAbstract
The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [MnIII2MnII] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn-carboxylate SCM with a linear architecture. This journal is © the Partner Organisations 2014.