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Synthesis and self-photooxygenation of alkenyl-linked [60]fullerene derivatives. A regioselective ene reaction
(2002)
(equation presented) Alkenyl-linked C60 derivatives undergo self-photooxygenation regioselectively, by the preferential abstraction of allylic hydrogens on the fullerene side of the double bond.
Characterization and magnetic properties of a "super stable" radical 1,3-diphenyl-7-trifluoromethyl-1,4-dihydro-1,2,4-benzotriazin-4-yl
(2011)
1,3-Diphenyl-7-trifluoromethyl-1,4-dihydro-1,2,4-benzotriazin-4-yl (4), prepared in SSSShigh yield via the catalytic oxidation of the corresponding amidrazone 5 by using Pd/C (1.6 mol ss%) and 1,8-diazabicyclo[5.4.0]undec-7-ene ...
Stable N- and N/S-Rich Heterocyclic Radicals: Synthesis and Applications
(2016)
Over the last few decades the number of stable heterocyclic neutral radicals has dramatically increased. There have been significant efforts to use these unusual open-shell compounds in a broad array of applications that ...
The phenol steam reforming reaction towards H2 production on natural calcite
(2009)
The steam reforming of phenol towards H2 production was studied in the 650-800 °C range over a natural pre-calcined (air, 850 °C) calcite material. The effects of reaction temperature, water, hydrogen, and carbon dioxide ...
A comparative study of the steam reforming of phenol towards H2 production over natural calcite, dolomite and olivine materials
(2010)
Pre-calcined (air, 850 °C) naturally occurring calcite, dolomite and olivine materials were studied for phenol steam reforming towards H2 production. The effect of reaction temperature, feed volume flow rate, and hydrogen ...
Thorium determination in water samples by liquid scintillation counting after its separation by cloud point extraction
(2011)
The aim of this study is the separation and pre-concentration of thorium from aqueous solutions by cloud point extraction (CPE) and its the radiometric determination by liquid scintillation counting (LSC). For CPE, tributyl ...
The effects of P-poisoning of CexZr1-xO2 on the transient oxygen storage and release kinetics
(2013)
The present work reports on the investigation of the effects of chemical poisoning of CexZr1-xO2 solids by phosphorous (P) on the kinetics of oxygen storage and release (OSR) of the thus derived P-contaminated solids, as ...
Macrocyclic malonates. A new family of tethers for the regio- and diastereoselective functionalization of [60]fullerene
(2006)
The tether-directed remote functionalization of C60 has been investigated by using cyclic bis- and trismalonate tethers. The reactive malonate groups are connected with alkyl spacers and their synthesis was performed in ...
A chiral dumbbell shaped bis(fullerene) oligoelectrolyte
(2007)
The first icosacationic bis(fullerene) whose water solubility is provided by twenty peripheral ammonium groups has a rigid, almost cylindrical shape and was synthesized by connecting two fullerene cores with a chiral ...