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"Squaring the clusters": A Mn III 4Ni II 4 molecular square from nickel(ii)-induced structural transformation of a Mn II/III/IV 12 cage
(2012)
A Mn III 4Ni II 4 molecular square exhibiting slow magnetization relaxation has been prepared from the reaction of a Mn II 4Mn III 6Mn IV 2 cluster and a simple Ni II source. © The Royal Society of Chemistry 2012.
Approaches to molecular magnetic materials from the use of cyanate groups in higher oxidation state metal cluster chemistry: Mn14 and Mn 16
(2013)
The initial employment of cyanato groups in higher oxidation state manganese cluster chemistry, in conjunction with the gem-diolate form of di-2-pyridylketone or 2,6-diacetylpyridine dioxime chelate ligands, has afforded ...
Synthesis of sulfur containing analogues of the soluble guanylate cyclase inhibitor 8-bromo-4H-[1,2,4]oxadiazolo[3,4-c][1,4]benzoxazin-1-one NS2028
(2011)
Sulfur analogues of the soluble guanylate cyclase (sGC) inhibitor NS2028 1a are synthesized. Treating 8-bromo-2H-benzo[b][1,4]oxazin-3(4H)-one oxime (6) with 1,1′-thiocarbonyldiimidazole (1.1 equiv) gave the carbamothioate ...
Flexible lanthanide MOFs as highly selective and reusable liquid MeOH sorbents
(2013)
A series of new 3-D Ln3+ metal-organic frameworks (MOFs), which are based on the semi-rigid ligand H3CIP [H3CIP = 5-(4-carboxybenzylideneamino)isophthalic acid], [Ln2(CIP) 2(DMF)4-x(H2O)x] (Ln3+ = La3+, Ce3+, Pr3+, Sm3+, ...
Assessment of organotins against the linoleic acid, glutathione and CT-DNA
(2014)
The already known di-n-butyltin(IV) complex of the chiral anti-inflammatory drug naproxen (Hnapr) of formula [(n-Bu-)2Sn(nap)2] (1), was re-synthesized here with an alternative method and it was used for the assessment of ...
A [Mn32] double-decker wheel
(2011)
Inventing the double wheel: A mixed-valent [Mn32] cluster with a very rare "double-decker" wheel topology (see its metal-oxygen core: MnIII blue, MnII pink, O red) is reported. It is by far the highest-nuclearity example ...
New Zn 2+ metal organic frameworks with unique network topologies from the combination of trimesic acid and amino-alcohols
(2012)
A series of new Zn 2+-trimesate (btc 3-) metal organic frameworks (MOFs) has been isolated in the presence of various amino-alcohols under solvothermal conditions. Thus, the reaction of ZnCl 2 with trimesic acid (H 3btc) ...
Synthesis and structural characterization of a metal cluster and a coordination polymer based on the [Mn6(μ4-O) 2]10+ Unit
(2010)
A new 1-D coordination polymer { [Mn6O2(O 2CMe)10 (H2O)4] 2.5 H 2O}λ (1 2.5 H2O) and the cluster [Mn 6O2(O2(O2CPh) 10(py) 2(MeCN)(H2O)] 2MeCN (2 2MeCN) are reported. Both compounds were synthesized by room temperature ...
A 1-D coordination polymer based on a Mn40 octagonal super-structure
(2013)
A 1-D coordination polymer, constructed using a combination of diols and phenolic oximes, contains a novel [Mn9] sub-unit, a nanosized [Mn40] octagonal super-structure and a [Mn21] repeating unit. © 2013 The Royal Society ...
Insertion of functional groups into a Nd 3+ metal-organic framework via single-crystal-to-single-crystal coordinating solvent exchange
(2012)
Single-crystal-to-single-crystal (SCSC) transformations represent some of the most fascinating phenomena in chemistry. They are not only intriguing from a basic science point of view but also provide a means to modify or ...