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dc.contributor.authorDemetriou, M.en
dc.contributor.authorBerezin, A. A.en
dc.contributor.authorKoutentis, P. A.en
dc.contributor.authorKrasia-Christoforou, T.en
dc.creatorDemetriou, M.en
dc.creatorBerezin, A. A.en
dc.creatorKoutentis, P. A.en
dc.creatorKrasia-Christoforou, T.en
dc.date.accessioned2019-05-06T12:23:31Z
dc.date.available2019-05-06T12:23:31Z
dc.date.issued2014
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/48307
dc.description.abstractThe stable free radical polymerization (SFRP) process based on (1,3-diphenyl-1,4-dihydro-1,2,4-benzotriazin-4-yl), the so-called 'Blatter radical', and several C-7 substituted derivatives is introduced for the first time for the polymerization of styrene. Polystyrenes characterized by polydispersity indices in the 1.05-1.27 range were obtained in the presence of the Blatter radical and its derivatives containing CF3, Ph, Fur-2-yl and 4-PhC6H4 substituents, while polymerization proceeded either in a non-controlled manner or in very low polymerization yields in the presence of derivatives containing halogen (Cl, Br, I) substituents. This preliminary investigation, demonstrating the potential use of the Blatter radical and its derivatives in mediated SFRP, creates new opportunities to design and develop radicals to optimize performance in such polymerization processes. © 2013 Society of Chemical Industry.en
dc.language.isoengen
dc.sourcePolymer Internationalen
dc.subjectPolydispersity indicesen
dc.subjectFree radical polymerizationen
dc.subjectAtom transfer radical polymerizationen
dc.subjectBenzotriazinyl radicalen
dc.subjectBenzotriazinyl radicalsen
dc.subjectBlatter radicalen
dc.subjectBromineen
dc.subjectBromine compoundsen
dc.subjectChlorineen
dc.subjectControlled radical polymerizationen
dc.subjectIodineen
dc.subjectPolymerization processen
dc.subjectPolystyreneen
dc.subjectPolystyrenesen
dc.subjectProcess-baseden
dc.subjectStable free radical polymerizationen
dc.subjectStyreneen
dc.titleBenzotriazinyl-mediated controlled radical polymerization of styreneen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1002/pi.4566
dc.description.volume63
dc.description.startingpage674
dc.description.endingpage679
dc.author.facultyΠολυτεχνική Σχολή / Faculty of Engineering
dc.author.departmentΤμήμα Μηχανικών Μηχανολογίας και Κατασκευαστικής / Department of Mechanical and Manufacturing Engineering
dc.type.uhtypeArticleen
dc.contributor.orcidKrasia-Christoforou, T. [0000-0002-9915-491X]
dc.description.totalnumpages674-679


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