dc.contributor.author | Tzitzios, V. | en |
dc.contributor.author | Kostoglou, N. | en |
dc.contributor.author | Giannouri, M. | en |
dc.contributor.author | Basina, G. | en |
dc.contributor.author | Tampaxis, C. | en |
dc.contributor.author | Charalambopoulou, Georgia | en |
dc.contributor.author | Steriotis, T. | en |
dc.contributor.author | Polychronopoulou, K. | en |
dc.contributor.author | Doumanidis, C. C. | en |
dc.contributor.author | Mitterer, C. | en |
dc.contributor.author | Rebholz, Claus | en |
dc.creator | Tzitzios, V. | en |
dc.creator | Kostoglou, N. | en |
dc.creator | Giannouri, M. | en |
dc.creator | Basina, G. | en |
dc.creator | Tampaxis, C. | en |
dc.creator | Charalambopoulou, Georgia | en |
dc.creator | Steriotis, T. | en |
dc.creator | Polychronopoulou, K. | en |
dc.creator | Doumanidis, C. C. | en |
dc.creator | Mitterer, C. | en |
dc.creator | Rebholz, Claus | en |
dc.date.accessioned | 2019-05-06T12:24:46Z | |
dc.date.available | 2019-05-06T12:24:46Z | |
dc.date.issued | 2017 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/48909 | |
dc.description.abstract | A nanoporous metal–organic framework material, exhibiting an IRMOF-1 type crystalline structure, was prepared by following a direct solvothermal synthesis approach, using zinc nitrate and terephthalic acid as precursors and dimethylformamide as solvent, combined with supercritical CO2 activation and vacuum outgassing procedures. A series of advanced characterization methods were employed, including scanning electron microscopy, Fourier-transform infrared radiation spectroscopy and X-ray diffraction, in order to study the morphology, surface chemistry and structure of the IRMOF-1 material directly upon its synthesis. Porosity properties, such as Brunauer–Emmet–Teller (BET) specific area (∼520 m2/g) and micropore volume (∼0.2 cm3/g), were calculated for the activated sample based on N2 gas sorption data collected at 77 K. The H2 storage performance was preliminary assessed by low-pressure (0–1 bar) H2 gas adsorption and desorption measurements at 77 K. The activated IRMOF-1 material of this study demonstrated a fully reversible H2 sorption behavior combined with an adequate gravimetric H2 uptake relative to its BET specific area, thus achieving a value of ∼1 wt.% under close-to-atmospheric pressure conditions. © 2017 Hydrogen Energy Publications LLC | en |
dc.language.iso | eng | en |
dc.source | International Journal of Hydrogen Energy | en |
dc.subject | Carbon dioxide | en |
dc.subject | Structure | en |
dc.subject | Characterization | en |
dc.subject | Fourier series | en |
dc.subject | X ray diffraction | en |
dc.subject | Crystalline materials | en |
dc.subject | Scanning electron microscopy | en |
dc.subject | Adsorption | en |
dc.subject | Porosity | en |
dc.subject | Digital storage | en |
dc.subject | Gas adsorption | en |
dc.subject | Hydrogen storage | en |
dc.subject | Structure (composition) | en |
dc.subject | Fourier transform infra reds | en |
dc.subject | Surface chemistry | en |
dc.subject | Atmospheric pressure | en |
dc.subject | Adsorption and desorptions | en |
dc.subject | Brunauer emmet tellers | en |
dc.subject | Characterization methods | en |
dc.subject | Infrared radiation | en |
dc.subject | IRMOF-1 | en |
dc.subject | Metal organic framework | en |
dc.subject | Organometallics | en |
dc.subject | Solvothermal synthesis | en |
dc.subject | Surface chemistry and structures | en |
dc.title | Solvothermal synthesis, nanostructural characterization and gas cryo-adsorption studies in a metal–organic framework (IRMOF-1) material | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1016/j.ijhydene.2017.04.059 | |
dc.description.volume | 42 | |
dc.description.startingpage | 23899 | |
dc.description.endingpage | 23907 | |
dc.author.faculty | Πολυτεχνική Σχολή / Faculty of Engineering | |
dc.author.department | Τμήμα Μηχανικών Μηχανολογίας και Κατασκευαστικής / Department of Mechanical and Manufacturing Engineering | |
dc.type.uhtype | Article | en |
dc.contributor.orcid | Charalambopoulou, Georgia [0000-0001-5236-1500] | |
dc.description.totalnumpages | 23899-23907 | |
dc.gnosis.orcid | 0000-0001-5236-1500 | |