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Spin-triplet excitons in 1,3-diphenyl-7-(fur-2-yl)-1,4-dihydro-1,2,4- benzotriazin-4-yl

dc.contributor.authorConstantinides, Christos P.en
dc.contributor.authorCarter, E.en
dc.contributor.authorMurphy, D. M.en
dc.contributor.authorManoli, Mariaen
dc.contributor.authorLeitus, G. M.en
dc.contributor.authorBendikov, M.en
dc.contributor.authorRawson, J. M.en
dc.contributor.authorKoutentis, Panayiotis Andreasen
dc.creatorConstantinides, Christos P.en
dc.creatorCarter, E.en
dc.creatorMurphy, D. M.en
dc.creatorManoli, Mariaen
dc.creatorLeitus, G. M.en
dc.creatorBendikov, M.en
dc.creatorRawson, J. M.en
dc.creatorKoutentis, Panayiotis Andreasen
dc.date.accessioned2019-11-21T06:17:49Z
dc.date.available2019-11-21T06:17:49Z
dc.date.issued2013
dc.identifier.issn1359-7345
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55358
dc.description.abstract7-(Fur-2-yl)benzotriazinyl 1 is the first example of a hydrazyl radical dimer with a thermally accessible triplet state. The triplet exciton (|D| = 0.018 cm-1, |E| = 0.001 cm-1) was observed by solid-state VT-EPR spectroscopy between 5 and 140 K. VT crystallography, DFT calculations and magnetic susceptibility studies reveal a strong temperature dependence of the intra-dimer exchange interaction with J/k ∼ -254 + 0.0007T2. © 2013 The Royal Society of Chemistry.en
dc.sourceChemical Communicationsen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84883325877&doi=10.1039%2fc3cc44899a&partnerID=40&md5=44ba3c6456f950fe9a95d23a76fa5037
dc.subjectarticleen
dc.subjectunclassified drugen
dc.subjectmagnetismen
dc.subjecttemperature dependenceen
dc.subjectroom temperatureen
dc.subjectX ray diffractionen
dc.subjectX ray crystallographyen
dc.subjecttemperatureen
dc.subjectelectron spin resonanceen
dc.subjectsolid stateen
dc.subjectradicalen
dc.subjectdimeren
dc.subjecthigh temperatureen
dc.subject1,2,4 benzotriazine derivativeen
dc.subject1,3 diphenyl 7 (fur 2 yl) 1,4 dihydro 1,2,4 benzotriazin 4 ylen
dc.subjectferroceneen
dc.titleSpin-triplet excitons in 1,3-diphenyl-7-(fur-2-yl)-1,4-dihydro-1,2,4- benzotriazin-4-ylen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1039/c3cc44899a
dc.description.volume49
dc.description.issue77
dc.description.startingpage8662
dc.description.endingpage8664
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :22</p>en
dc.source.abbreviationChem.Commun.en
dc.contributor.orcidKoutentis, Panayiotis Andreas [0000-0002-4652-7567]
dc.contributor.orcidConstantinides, Christos P. [0000-0001-6364-1102]
dc.gnosis.orcid0000-0002-4652-7567
dc.gnosis.orcid0000-0001-6364-1102


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