dc.contributor.author | Hadjiloizou, P. | en |
dc.contributor.author | Pashalidis, Ioannis | en |
dc.creator | Hadjiloizou, P. | en |
dc.creator | Pashalidis, Ioannis | en |
dc.date.accessioned | 2019-11-21T06:19:15Z | |
dc.date.available | 2019-11-21T06:19:15Z | |
dc.date.issued | 2007 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55525 | |
dc.description.abstract | The interaction of the clinically used 1,2-dimethyl-3-hydroxypyrid-4-one with trivalent europium Eu(III), was investigated by using potentiometric and spectroscopic methods. The stability constants of the EuLn (3-n)+ complexes determined by spectroscopic and potentiometric measurements were found to be log β11 = 6.5±0.3 and log β12 = 12.0±0.5. However, at pH ≥ 5, hydrolysis of the Eu-L complexes starts, resulting in the formation of needle-type, yellow crystals. The low solubility of the Eu-L complexes in the neutral pH range is disadvantageous with respect to the use of deferiprone as chelating agent for decorporation of trivalent f-elements. © 2007 Springer Science+Business Media, Inc. | en |
dc.source | Journal of Radioanalytical and Nuclear Chemistry | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-34547622804&doi=10.1007%2fs10967-007-0908-4&partnerID=40&md5=aea3e6b8a2992e53b47e008d92a78bfa | |
dc.subject | article | en |
dc.subject | complex formation | en |
dc.subject | spectroscopy | en |
dc.subject | solubility | en |
dc.subject | chelating agent | en |
dc.subject | potentiometry | en |
dc.subject | hydrolysis | en |
dc.subject | chelation | en |
dc.subject | deferiprone | en |
dc.subject | europium | en |
dc.title | Interaction between 1,2-dimethyl-3-hydroxypyrid-4-one and europium(III) | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1007/s10967-007-0908-4 | |
dc.description.volume | 273 | |
dc.description.issue | 3 | |
dc.description.startingpage | 553 | |
dc.description.endingpage | 556 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :1</p> | en |
dc.source.abbreviation | J.Radioanal.Nucl.Chem. | en |
dc.contributor.orcid | Pashalidis, Ioannis [0000-0002-7587-6395] | |
dc.gnosis.orcid | 0000-0002-7587-6395 | |