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The production and decay kinetics of CIOO in water and freon-11: A time-resolved resonance Raman study

dc.contributor.authorHayes, Sophia C.en
dc.contributor.authorThomsen, C. L.en
dc.contributor.authorReid, P. J.en
dc.creatorHayes, Sophia C.en
dc.creatorThomsen, C. L.en
dc.creatorReid, P. J.en
dc.date.accessioned2019-11-21T06:19:21Z
dc.date.available2019-11-21T06:19:21Z
dc.date.issued2001
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55547
dc.description.abstractThe production and decay kinetics of ClOO in water and freon-11 were studied using time-resolved resonance Raman (TRRR) spectroscopy. The formation of ClOO following OClO photoexcitation at 390 nm was investigated using resonance Raman spectra obtained with a 260 nm probe beam. Aqueous ClOO appeared and decayed with time constants of 27.9±4.5 ps and 398±50 ps. The ClOO kinetics was found to be much slower in freon-11. The germinate recombination quantum yield for ClOO production was reduced in freon-11 relative to water. Photoisomerization of OClO followed by excited state internal conversion was also proposed for formation of ground state ClOO.en
dc.sourceJournal of Chemical Physicsen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-0035936355&doi=10.1063%2f1.1418733&partnerID=40&md5=07549191096ed730c1eac746711ac1ae
dc.subjectMathematical modelsen
dc.subjectComputational methodsen
dc.subjectApproximation theoryen
dc.subjectChlorine compoundsen
dc.subjectReaction kineticsen
dc.subjectWateren
dc.subjectRaman scatteringen
dc.subjectRaman spectroscopyen
dc.subjectOrganic solventsen
dc.subjectSolid state lasersen
dc.subjectPyrolysisen
dc.subjectPhotolysisen
dc.subjectGround stateen
dc.subjectMolecular vibrationsen
dc.subjectIsomerizationen
dc.subjectFreonsen
dc.subjectTime-resolved resonance Raman (TRRR) spectroscopyen
dc.titleThe production and decay kinetics of CIOO in water and freon-11: A time-resolved resonance Raman studyen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1063/1.1418733
dc.description.volume115
dc.description.issue24
dc.description.startingpage11228
dc.description.endingpage11238
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :17</p>en
dc.source.abbreviationJ.Chem.Phys.en
dc.contributor.orcidHayes, Sophia C. [0000-0002-2809-6193]
dc.gnosis.orcid0000-0002-2809-6193


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