Enantioseparations in open-tubular capillary electrochromatography: Recent advances and applications
Date
2016Source
Journal of Chromatography AVolume
1467Pages
145-154Google Scholar check
Keyword(s):
Metadata
Show full item recordAbstract
This review highlights recent advances and applications in open-tubular capillary electrochromatography (OT-CEC) for enantioseparations during the last decade. Although extensive research has been conducted in the area of separations by use of CEC, and a big number of reviews have been published, there is not a review on exclusively the use of chiral stationary phases (CSPs) in OT-CEC for enantioseparations. Therefore, in this review, the design and synthesis of different CSPs are presented, and their potential applications in OT-CEC for enantioseparations are discussed. The different approaches to CSP development include chiral nanomaterials, porous layers, molecular imprinting, sol-gel technique, polyelectrolyte multilayer coating, polymeric coating and others. © 2016 Elsevier B.V.
Collections
Cite as
Related items
Showing items related by title, author, creator and subject.
-
Article
Use of chiral amino acid ester-based ionic liquids as chiral selectors in CE
Stavrou, Ioannis J.; Kapnissi‐Christodoulou, Constantina P. (2013)In this study, the applicability of a chiral ionic liquid (CIL) as the sole chiral selector in CE was investigated for the first time. In particular, five amino acid ester-based CILs were synthesized and used as additives ...
-
Article
Chiral separation of the clinically important compounds fucose and pipecolic acid using ce: Determination of the most effective chiral selector
Hadjistasi, Christoforos A.; Stavrou, Ioannis J.; Stefan-Van Staden, R. -I; Aboul‐Enein, Hassan Y.; Kapnissi‐Christodoulou, Constantina P. (2013)In this study, simple electrophoretic methods were developed for the chiral separation of the clinically important compounds fucose and pipecolic acid. In recent years, these analytes, and particularly their individual ...
-
Article
Facile preparation of polysaccharide-coated capillaries using a room temperature ionic liquid for chiral separations
Stavrou, Ioannis J.; Moore, L.; Fernand, V. E.; Kapnissi‐Christodoulou, Constantina P.; Warner, I. M. (2013)In this study, the dissolution of polysaccharides into an ionic liquid was investigated and applied as a coating onto the capillary walls of a fused-silica capillary in open-tubular CEC. The coating was evaluated by examining ...