Enantioseparations in open-tubular capillary electrochromatography: Recent advances and applications
SourceJournal of Chromatography A
Google Scholar check
MetadataShow full item record
This review highlights recent advances and applications in open-tubular capillary electrochromatography (OT-CEC) for enantioseparations during the last decade. Although extensive research has been conducted in the area of separations by use of CEC, and a big number of reviews have been published, there is not a review on exclusively the use of chiral stationary phases (CSPs) in OT-CEC for enantioseparations. Therefore, in this review, the design and synthesis of different CSPs are presented, and their potential applications in OT-CEC for enantioseparations are discussed. The different approaches to CSP development include chiral nanomaterials, porous layers, molecular imprinting, sol-gel technique, polyelectrolyte multilayer coating, polymeric coating and others. © 2016 Elsevier B.V.
Showing items related by title, author, creator and subject.
Stavrou, Ioannis J.; Kapnissi‐Christodoulou, Constantina P. (2013)In this study, the applicability of a chiral ionic liquid (CIL) as the sole chiral selector in CE was investigated for the first time. In particular, five amino acid ester-based CILs were synthesized and used as additives ...
Chiral separation of the clinically important compounds fucose and pipecolic acid using ce: Determination of the most effective chiral selector Hadjistasi, Christoforos A.; Stavrou, Ioannis J.; Stefan-Van Staden, R. -I; Aboul‐Enein, Hassan Y.; Kapnissi‐Christodoulou, Constantina P. (2013)In this study, simple electrophoretic methods were developed for the chiral separation of the clinically important compounds fucose and pipecolic acid. In recent years, these analytes, and particularly their individual ...
Facile preparation of polysaccharide-coated capillaries using a room temperature ionic liquid for chiral separations Stavrou, Ioannis J.; Moore, L.; Fernand, V. E.; Kapnissi‐Christodoulou, Constantina P.; Warner, I. M. (2013)In this study, the dissolution of polysaccharides into an ionic liquid was investigated and applied as a coating onto the capillary walls of a fused-silica capillary in open-tubular CEC. The coating was evaluated by examining ...