dc.contributor.author | Kapnissi‐Christodoulou, Constantina P. | en |
dc.contributor.author | Zhu, X. | en |
dc.contributor.author | Warner, I. M. | en |
dc.creator | Kapnissi‐Christodoulou, Constantina P. | en |
dc.creator | Zhu, X. | en |
dc.creator | Warner, I. M. | en |
dc.date.accessioned | 2019-11-21T06:19:47Z | |
dc.date.available | 2019-11-21T06:19:47Z | |
dc.date.issued | 2003 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55645 | |
dc.description.abstract | This review represents a summary of recent progress in open-tubular capillary electro-chromatography (OT-CEC) for chiral and achiral separations. The OT-CEC approach is an alternative to packed-CEC that could eliminate the problems associated with retaining frits and silica particles. In OT-CEC, the stationary phase is immobilized on the inner walls of the capillary. Preparation of the stationary phase is critical for OT-CEC. The preparation methods for capillary columns include (i)adsorption, (ii) covalent bonding and/or cross-linking, (iii) porous layers, (iv) chemical bonding after etching, (v) sol-gel, and (vi) molecular imprinting. Major developments, potential applications, technical difficulties and advantages associated with these wall coatings in OT-CEC are presented. In addition, the coupling of OT-CEC with mass spectrometry (MS) is briefly reviewed. Several applications of this hyphenated technique for analytical separations are also summarized. | en |
dc.source | Electrophoresis | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0345827802&partnerID=40&md5=27934102f05f31860c59a784c4d17d46 | |
dc.subject | Review | en |
dc.subject | surfactant | en |
dc.subject | Polymers | en |
dc.subject | Chromatography | en |
dc.subject | liquid chromatography | en |
dc.subject | covalent bond | en |
dc.subject | porosity | en |
dc.subject | analytic method | en |
dc.subject | chemical binding | en |
dc.subject | cross linking | en |
dc.subject | cellulose | en |
dc.subject | mass spectrometry | en |
dc.subject | adsorption | en |
dc.subject | chirality | en |
dc.subject | silicon dioxide | en |
dc.subject | capillary electrochromatography | en |
dc.subject | separation technique | en |
dc.subject | gas chromatography | en |
dc.subject | cyclodextrin | en |
dc.subject | Electrophoresis, Capillary | en |
dc.subject | enantioselectivity | en |
dc.subject | benzodiazepine derivative | en |
dc.subject | Open-tubular capillary electrochromatography | en |
dc.subject | temazepam | en |
dc.subject | Analytical separations | en |
dc.subject | chlordiazepoxide | en |
dc.subject | diazepam | en |
dc.subject | etozolin | en |
dc.subject | hexobarbital | en |
dc.subject | laudanosine | en |
dc.subject | molecular imprinting | en |
dc.subject | oxazepam | en |
dc.subject | piprozolin | en |
dc.subject | propranolol | en |
dc.subject | supercritical fluid chromatography | en |
dc.title | Analytical separations in open-tubular capillary electrochromatography | en |
dc.type | info:eu-repo/semantics/article | |
dc.description.volume | 24 | |
dc.description.issue | 22-23 | |
dc.description.startingpage | 3917 | |
dc.description.endingpage | 3934 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :70</p> | en |
dc.source.abbreviation | Electrophoresis | en |
dc.contributor.orcid | Kapnissi‐Christodoulou, Constantina P. [0000-0003-3755-1052] | |
dc.gnosis.orcid | 0000-0003-3755-1052 | |