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Investigation on uranyl interaction with bioactive ligands. Synthesis and structural studies of the uranyl complexes with glycine and N-(2-mercaptopropionyl)glycine

dc.contributor.authorKeramidas, Anastasios D.en
dc.contributor.authorRikkou, Maria P.en
dc.contributor.authorDrouza, Chryssoulaen
dc.contributor.authorRaptopoulou, Catherine P.en
dc.contributor.authorTerzis, Arisen
dc.contributor.authorPashalidis, Ioannisen
dc.creatorKeramidas, Anastasios D.en
dc.creatorRikkou, Maria P.en
dc.creatorDrouza, Chryssoulaen
dc.creatorRaptopoulou, Catherine P.en
dc.creatorTerzis, Arisen
dc.creatorPashalidis, Ioannisen
dc.date.accessioned2019-11-21T06:19:54Z
dc.date.available2019-11-21T06:19:54Z
dc.date.issued2002
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55668
dc.description.abstractThree new uranium(VI) compounds have been prepared with glycine (Hgly), N-(2-mercaptopropionyl)glycine (Hmpg) and 2,2′-dithiobis(N-propionylglycine) (tpg). The crystal structure of [UO2(Hgly)2Cl2] has been solved, revealing the uranium atom to be seven-co-ordinated. The two zwitterionic glycines are coordinated to uranium atom by the carboxylate groups, one in a monodentate and the other in a bidentate mode. Solid state studies and low temperature 1H, 13C, 2D COSY and HMQC solution NMR spectra of the [UO2(mpg)(CH3COO)], show that mpg coordinates uranium atom by the carboxylate group.en
dc.sourceRadiochimica Actaen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-0038041342&partnerID=40&md5=976caed85504d1d53c6223cc557ac622
dc.subjectconference paperen
dc.subjectunclassified drugen
dc.subjectsynthesisen
dc.subjectcrystal structureen
dc.subjectnuclear magnetic resonance spectroscopyen
dc.subjectX ray crystallographyen
dc.subjectinfrared spectroscopyen
dc.subjectliganden
dc.subjectsolid stateen
dc.subjectGlycineen
dc.subjecttioproninen
dc.subjectUraniumen
dc.subjectcarboxylic acid derivativeen
dc.subjectglycine derivativeen
dc.subject2,2' dithiobis(n propionylglycine)en
dc.subject2,2′-dithiobis (N-propionylglycine)en
dc.subjectN-(2-mercaptopropionyl)glycineen
dc.titleInvestigation on uranyl interaction with bioactive ligands. Synthesis and structural studies of the uranyl complexes with glycine and N-(2-mercaptopropionyl)glycineen
dc.typeinfo:eu-repo/semantics/article
dc.description.volume90
dc.description.issue9-11
dc.description.startingpage549
dc.description.endingpage554
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :19</p>en
dc.source.abbreviationRadiochim.Actaen
dc.contributor.orcidPashalidis, Ioannis [0000-0002-7587-6395]
dc.contributor.orcidKeramidas, Anastasios D. [0000-0002-0446-8220]
dc.contributor.orcidDrouza, Chryssoula [0000-0002-2630-4323]
dc.contributor.orcidRaptopoulou, Catherine P. [0000-0002-8775-5427]
dc.gnosis.orcid0000-0002-7587-6395
dc.gnosis.orcid0000-0002-0446-8220
dc.gnosis.orcid0000-0002-2630-4323
dc.gnosis.orcid0000-0002-8775-5427


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