Synthesis of [(4-Chloro-5H-1,2,3-dithiazol-5-ylidene)amino]azines
AuthorKoutentis, Panayiotis Andreas
Koyioni, Maria G.
Michaelidou, Sophia S.
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The reactions of 2-, 3- and 4-aminopyridines with 4,5-dichloro-1,2,3- dithiazolium chloride (Appel salt) 4 to give N-(4-chloro-5H-1,2,3-dithiazol-5- ylidene)pyridin-Xamines 1a (X = 2), 1g (X = 3) and 1k (X = 4) were optimized with respect to base, temperature and reaction time. Based on these conditions a total of thirteen [(dithiazolylidene) amino]azines 1a-m were prepared and fully characterized. © 2011 by the authorslicensee MDPI, Basel, Switzerland.