dc.contributor.author | Patrickios, Costas S. | en |
dc.contributor.author | Forder, C. | en |
dc.contributor.author | Armes, S. P. | en |
dc.contributor.author | Billingham, N. C. | en |
dc.creator | Patrickios, Costas S. | en |
dc.creator | Forder, C. | en |
dc.creator | Armes, S. P. | en |
dc.creator | Billingham, N. C. | en |
dc.date.accessioned | 2019-11-21T06:22:07Z | |
dc.date.available | 2019-11-21T06:22:07Z | |
dc.date.issued | 1998 | |
dc.identifier.issn | 0887-624X | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/55984 | |
dc.description.abstract | Water-soluble amphiphilic diblock copolymers were synthesized by the living cationic polymerization of methyl vinyl ether (hydrophilic block) and its subsequent termination with n-alcohols of chain lengths varying from one to eight, and three n-alkyl carboxylic acids with 10, 12, and 18 carbon atoms. Additionally, water and ethylene glycol were tested as terminating agents. The extent of the functionalization was determined using 1H NMR spectroscopy. The cloud points of 1% w/w aqueous solutions of the polymers as determined by turbidimetry decreased from 32 to 21°C as the number of carbon atoms of the terminating agent increased. Aqueous GPC revealed micellization of the stearic acid-terminated block copolymer, while the other block copolymers existed mainly as unimers. © 1998 John Wiley & Sons, Inc. | en |
dc.source | Journal of Polymer Science, Part A: Polymer Chemistry | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0032188424&partnerID=40&md5=ef209bcc6873fcc8a23ebd413287670d | |
dc.subject | Synthesis (chemical) | en |
dc.subject | Micelles | en |
dc.subject | Amphiphiles | en |
dc.subject | Block copolymers | en |
dc.subject | Nuclear magnetic resonance spectroscopy | en |
dc.subject | Water | en |
dc.subject | Cloud points | en |
dc.subject | Stearic acid | en |
dc.subject | Glycols | en |
dc.subject | Gel permeation chromatography | en |
dc.subject | Molecular structure | en |
dc.subject | Living cationic polymerization | en |
dc.subject | Cationic polymerization | en |
dc.subject | Vinyl resins | en |
dc.subject | End-functionalized polymers | en |
dc.subject | Acetal resins | en |
dc.subject | Acetals | en |
dc.subject | Diblock copolymers | en |
dc.subject | Nonionic polymeric surfactants | en |
dc.subject | Poly(methyl vinyl ether) | en |
dc.subject | Polymethylvinylethers | en |
dc.subject | Water-soluble polymers | en |
dc.title | Near-monodisperse, n-alkyl, end-functionalized poly(methyl vinyl ether)s: Synthesis by living cationic polymerization and solution characterization | en |
dc.type | info:eu-repo/semantics/article | |
dc.description.volume | 36 | |
dc.description.issue | 14 | |
dc.description.startingpage | 2547 | |
dc.description.endingpage | 2554 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :14</p> | en |
dc.source.abbreviation | J.Polym.Sci.Part A | en |
dc.contributor.orcid | Patrickios, Costas S. [0000-0001-8855-0370] | |
dc.gnosis.orcid | 0000-0001-8855-0370 | |