A novel aggregate of [Mn2(μ-O)2] units: [Mn8O10(O2CMe)6(H2O) 2(bpy)6]4+ with a serpentine core
Date
2003ISSN
1359-7345Source
Chemical CommunicationsVolume
9Issue
5Pages
580-581Google Scholar check
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The synthesis, characterization and initial reactivity studies are reported of the mixed-valence (MnIV 6MnIII 2) title compound, which possesses an unusual serpentine-like core and is the highest average oxidation state (+3.75) Mnx (x > 4) cluster to date.