dc.contributor.author | Tasiopoulos, Anastasios J. | en |
dc.contributor.author | Perlepes, Spyros P. | en |
dc.creator | Tasiopoulos, Anastasios J. | en |
dc.creator | Perlepes, Spyros P. | en |
dc.date.accessioned | 2019-11-21T06:23:08Z | |
dc.date.available | 2019-11-21T06:23:08Z | |
dc.date.issued | 2008 | |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/56194 | |
dc.description.abstract | The combination of diol-type ligands with paramagnetic transition metal ions has led to the isolation of a host of new homometallic and heterometallic clusters, high-spin molecules and single molecule magnets ranging in nuclearity from two to forty four and with spin ground states as large as S = 61/2. The ligands, whose cluster coordination chemistry is discussed in this article, are 1,3-propanediol and its derivatives, diethanolamine and its derivatives, pyridine-2,6-dimethanol and the gem-diol form of di-2-pyridyl ketone. The structural diversity of the complexes stems from the ability of the ligands to adopt a variety of bridging coordination modes depending on the positions of the two hydroxyl groups in the molecule, the presence/absence of extra donor groups and on the reaction conditions. Examples of 'true' reactivity chemistry involving clusters of diol-type ligands are also given. The activation of pyridine-2,6-dimethanol and di-2-pyridyl ketone by 3d-metal centres towards further reactions seems to be an emergent area of synthetic chemistry. © 2008 The Royal Society of Chemistry. | en |
dc.source | Dalton Transactions | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-54049105741&doi=10.1039%2fb805014g&partnerID=40&md5=3676a8461d5120688c7f3d2bce39c147 | |
dc.subject | Optical sensors | en |
dc.subject | Ketones | en |
dc.subject | Molecules | en |
dc.subject | Spin dynamics | en |
dc.subject | Metal ions | en |
dc.subject | Transition metal compounds | en |
dc.subject | Transition metals | en |
dc.subject | Chemical reactions | en |
dc.subject | Ligands | en |
dc.subject | Magnets | en |
dc.subject | Chemistry | en |
dc.subject | Coordination reactions | en |
dc.subject | Organic compounds | en |
dc.subject | Reaction conditions | en |
dc.subject | Pyridine | en |
dc.subject | Nuclearity | en |
dc.subject | Metal centres | en |
dc.subject | Pyridyl | en |
dc.subject | Bridging coordination modes | en |
dc.subject | Coordination chemistries | en |
dc.subject | Diethanolamine | en |
dc.subject | Donor groups | en |
dc.subject | Heterometallic clusters | en |
dc.subject | Hydroxyl groups | en |
dc.subject | Paramagnetic transitions | en |
dc.subject | Propanediol | en |
dc.subject | Ranging | en |
dc.subject | Single molecules | en |
dc.subject | Spin ground states | en |
dc.subject | Structural diversities | en |
dc.subject | Synthetic chemistries | en |
dc.title | Diol-type ligands as central 'players' in the chemistry of high-spin molecules and single-molecule magnets | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1039/b805014g | |
dc.description.issue | 41 | |
dc.description.startingpage | 5537 | |
dc.description.endingpage | 5555 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :124</p> | en |
dc.source.abbreviation | Dalton Trans. | en |
dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
dc.gnosis.orcid | 0000-0002-4804-3822 | |