High nuclearity structurally-related Mn supertetrahedral T4 aggregates
Ημερομηνία
2021-12-04Συγγραφέας
Skordi, KaterinaAnastassiades, Antonis
Fournet, Adeline D.
Fournet, Adeline D.
Schulze, Michael
Wernsdorfer, Wolfgang
Christou, George
Nastopoulos, Vassilios
Perlepes, Spyros P.
Papatriantafyllopoulou, Constantina
Tasiopoulos, Anastasios J.
ISSN
1359-7345Εκδότης
Royal Society of ChemistryPlace of publication
Cambridge, UKSource
Chemical communicationsVolume
57Issue
93Pages
12484-12487Google Scholar check
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Metadata
Εμφάνιση πλήρους εγγραφήςΕπιτομή
The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.