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Antiproliferative activity and apoptosis induction, of organo-antimony(III)–copper(I) conjugates, against human breast cancer cells
(2019)
Three known organo-antimony(III)–copper(I), mixed-metal small bioactive molecules (SBAMs) of formula [Cu(tpSb)3Cl] (1), [Cu2(tpSb)4Br2] (2) and [Cu2(tpSb)4I2] (3) (tpSb = triphenylstibine) were used for the clarification ...
Spin-Crossover Phenomenon in Microcrystals and Nanoparticles of a [Fe(2-mpz)2Ni(CN)4] Two-Dimensional Hofmann-Type Polymer: A Detailed Nano-Topographic Study
(2019)
The diamagnetic two-dimensional Hofmann-type metal–organic framework [ZnII(2-mpz)2Ni(CN)4] has been successfully synthesized along with its isostructural hysteretic spin-crossover FeII analogue in the form of both bulk ...
Homometallic {Mn10} and heterometallic {Mn6Ca4} supertetrahedra exhibiting an unprecedented {MnIII9MnII} oxidation state level and heterometal ions distribution
(2018)
Two novel decametallic clusters displaying a supertetrahedral structural core are discussed, a homometallic compound [MnIII9MnII(μ4-O)4(μ3-OMe)3(btH)3(ed)3(PhCO2)6]·6Η2Ο (1·6Η2Ο) (btH3 = (±)-1,2,4-butanetriol
Synthesis, characterization and cytotoxic properties of bismuth(III) chloride complexes with heterocyclic thioamides
(2018)
Bismuth(III) complexes of the formulae [BiCl3(MBZT)2] ·H2O} (1), {[BiCl2(µ2-Cl)(MMI)2]2·(CH3)2CO} (2), {[BiCl3(µ2-S-PYT)(PYT)]2} (3) {([BiCl2(MBZIM)4]+)·2(Cl-)·(H3O+) ·2H2O} (4) and [BiCl3(tHPMT)3] (5) (where MBZT: ...
Magnetic "Molecular Oligomers" Based on Decametallic Supertetrahedra: A Giant Mn49 Cuboctahedron and its Mn25Na4 Fragment
(2016)
Two nanosized Mn49 and Mn25Na4 clusters based on analogues of the high-spin (S=22) [MnIII 6MnII 4(μ4-O)4]18+ supertetrahedral core are reported. Mn49 and Mn25Na4 complexes consist of eight and four decametallic supertetrahedral ...
A [Mn32] double-decker wheel
(2011)
Inventing the double wheel: A mixed-valent [Mn32] cluster with a very rare "double-decker" wheel topology (see its metal-oxygen core: MnIII blue, MnII pink, O red) is reported. It is by far the highest-nuclearity example ...
New Zn 2+ metal organic frameworks with unique network topologies from the combination of trimesic acid and amino-alcohols
(2012)
A series of new Zn 2+-trimesate (btc 3-) metal organic frameworks (MOFs) has been isolated in the presence of various amino-alcohols under solvothermal conditions. Thus, the reaction of ZnCl 2 with trimesic acid (H 3btc) ...
Synthesis and structural characterization of a metal cluster and a coordination polymer based on the [Mn6(μ4-O) 2]10+ Unit
(2010)
A new 1-D coordination polymer { [Mn6O2(O 2CMe)10 (H2O)4] 2.5 H 2O}λ (1 2.5 H2O) and the cluster [Mn 6O2(O2(O2CPh) 10(py) 2(MeCN)(H2O)] 2MeCN (2 2MeCN) are reported. Both compounds were synthesized by room temperature ...