Regio- and stereoselective synthesis of enantiomerically pure fullerene tris-adducts with an inherently chiral e,e,e addition pattern
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The synthesis and flash column chromatographic separation of c enantiomerically pure tris-adducts of C60 with an e,e,e-addition pattern is achieved via cyclopropanation with chiral D3-symmetrical cyclo-tris(malonate) tethers. © The Royal Society of Chemistry 2005.