dc.contributor.author | Stoumpos, Constantinos C. | en |
dc.contributor.author | Stamatatos, Theocharis C. | en |
dc.contributor.author | Sartzi, H. | en |
dc.contributor.author | Roubeau, O. | en |
dc.contributor.author | Tasiopoulos, Anastasios J. | en |
dc.contributor.author | Nastopoulos, Vassilios | en |
dc.contributor.author | Teat, S. J. | en |
dc.contributor.author | Christou, George | en |
dc.contributor.author | Perlepes, Spyros P. | en |
dc.creator | Stoumpos, Constantinos C. | en |
dc.creator | Stamatatos, Theocharis C. | en |
dc.creator | Sartzi, H. | en |
dc.creator | Roubeau, O. | en |
dc.creator | Tasiopoulos, Anastasios J. | en |
dc.creator | Nastopoulos, Vassilios | en |
dc.creator | Teat, S. J. | en |
dc.creator | Christou, George | en |
dc.creator | Perlepes, Spyros P. | en |
dc.date.accessioned | 2019-11-21T06:23:01Z | |
dc.date.available | 2019-11-21T06:23:01Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | http://gnosis.library.ucy.ac.cy/handle/7/56171 | |
dc.description.abstract | The employment of the anion of methyl 2-pyridyl ketone oxime (mpko -) as a tridentate chelating/bridging ligand in manganese chemistry is described. The inorganic anion (Br-, ClO4-) used in the reaction affects the identity of the product. The reaction of MnBr2 and one equivalent of mpkoH in the presence of a base affords [Mn3(OMe)2(mpko)4Br2] (3), which is mixed-valence (2MnII, MnIV). The central MnIV atom in each of the two, crystallographically independent, centrosymmetric molecules is coordinated by four oximate oxygen atoms belonging to the η1:η1:η1:μ mpko- ligands, and two η1:μ MeO- groups, while six coordination at each terminal MnII atom is completed by four nitrogen atoms belonging to the 'chelating' part of two mpko- ligands, and one Br- ion. The MnII atoms have trigonal prismatic coordination geometry. The reaction of Mn(ClO4)2· 6H2O, mpkoH and OH- (1:2:1) in MeOH gives [Mn 8O4(OMe)(mpko)9(mpkoH)](ClO4) 4 (4), which is also mixed-valence (2MnII, 6Mn III) and possesses the novel [Mn8(μ3-O) 4(μ-OMe)(μ-OR″)2]11+ core. The latter possesses a U-shaped sequence of four fused {MnIIMn III2(μ3-O)}6+ triangular units, with a MnIII-MnIII edge being shared between the central triangles. Variable-temperature, solid-state dc and ac magnetic susceptibility studies were carried out on complexes 3 and 4. The dc susceptibility data for 3 in the 5.0-300 K range have been fit to a model with two J values, revealing weak ferromagnetic MnII⋯MnIV (J = +3.4 cm -1) and MnII⋯MnII (J′ = +0.3 cm-1) exchange interactions. Fitting of the magnetization vs. H/T data by matrix diagonalization and including only axial anisotropy (ZFS, D) gave ground state spin (S) and D values of S = 13/2, D = +0.17 cm-1 for 3 and S = 3, D = -0.09 cm-1 for 4. The combined work demonstrates the usefulness of mpko- in the preparation of interesting Mn clusters, without requiring the co-presence of carboxylate ligands. © The Royal Society of Chemistry 2009. | en |
dc.source | Dalton Transactions | en |
dc.source.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-62549085554&doi=10.1039%2fb813828a&partnerID=40&md5=9c2f628fc60980662f56e9aa645b944d | |
dc.subject | Employment | en |
dc.subject | article | en |
dc.subject | chemistry | en |
dc.subject | synthesis | en |
dc.subject | matrixes | en |
dc.subject | Manganese | en |
dc.subject | Ketones | en |
dc.subject | Manganese compounds | en |
dc.subject | Oxygen | en |
dc.subject | Magnetic susceptibility | en |
dc.subject | X ray crystallography | en |
dc.subject | Ligands | en |
dc.subject | pyridine derivative | en |
dc.subject | Pyridines | en |
dc.subject | electrochemistry | en |
dc.subject | organometallic compound | en |
dc.subject | Organometallic Compounds | en |
dc.subject | Crystallography, X-Ray | en |
dc.subject | Oximes | en |
dc.subject | Atoms | en |
dc.subject | Mixed valences | en |
dc.subject | Carboxylation | en |
dc.subject | Negative ions | en |
dc.subject | oxime | en |
dc.subject | Ground-state spins | en |
dc.subject | Mn clusters | en |
dc.subject | Nitrogen atoms | en |
dc.subject | Oxygen atoms | en |
dc.subject | AC magnetic susceptibilities | en |
dc.subject | Axial anisotropies | en |
dc.subject | Carboxylate ligands | en |
dc.subject | Centrosymmetric molecules | en |
dc.subject | Co presences | en |
dc.subject | Dc susceptibilities | en |
dc.subject | Diagonalization | en |
dc.subject | Inorganic anions | en |
dc.subject | J-values | en |
dc.subject | methyl 2 pyridyl ketone oxime | en |
dc.subject | methyl 2-pyridyl ketone oxime | en |
dc.subject | Prismatic coordinations | en |
dc.subject | Pyridyl | en |
dc.subject | U-shaped | en |
dc.subject | Variable temperatures | en |
dc.title | Employment of methyl 2-pyridyl ketone oxime in manganese non-carboxylate chemistry: MnII2MnIV and MnII 2MnIII6 complexes | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1039/b813828a | |
dc.description.issue | 6 | |
dc.description.startingpage | 1004 | |
dc.description.endingpage | 1015 | |
dc.author.faculty | 002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences | |
dc.author.department | Τμήμα Χημείας / Department of Chemistry | |
dc.type.uhtype | Article | en |
dc.description.notes | <p>Cited By :31</p> | en |
dc.source.abbreviation | Dalton Trans. | en |
dc.contributor.orcid | Tasiopoulos, Anastasios J. [0000-0002-4804-3822] | |
dc.contributor.orcid | Stamatatos, Theocharis C. [0000-0002-9798-9331] | |
dc.contributor.orcid | Nastopoulos, Vassilios [0000-0003-4190-1342] | |
dc.contributor.orcid | Stoumpos, Constantinos C. [0000-0001-8396-9578] | |
dc.gnosis.orcid | 0000-0002-4804-3822 | |
dc.gnosis.orcid | 0000-0002-9798-9331 | |
dc.gnosis.orcid | 0000-0003-4190-1342 | |
dc.gnosis.orcid | 0000-0001-8396-9578 | |