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Template Synthesis and Single-Molecule Magnetism Properties of a Complex with Spin S = 16 and a [Mn8O8]8+ Saddle-Like Core

dc.contributor.authorTasiopoulos, Anastasios J.en
dc.contributor.authorWernsdorfer, W.en
dc.contributor.authorMoulton, B.en
dc.contributor.authorZaworotko, M. J.en
dc.contributor.authorChristou, Georgeen
dc.creatorTasiopoulos, Anastasios J.en
dc.creatorWernsdorfer, W.en
dc.creatorMoulton, B.en
dc.creatorZaworotko, M. J.en
dc.creatorChristou, Georgeen
dc.date.accessioned2019-11-21T06:23:11Z
dc.date.available2019-11-21T06:23:11Z
dc.date.issued2003
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/56204
dc.description.abstractThe compound [CeIVMn8IIIO8(O2CMe)12(H2O)4]·4H2O (1·4H2O) has been obtained from a template synthesis involving the reaction of the chain polymer {[MnIII(OH)(O2CMe)2]·(MeCO2H)·(H2O)}n (3) with Ce(IV). Compound 1 contains a Mn8III loop inside which is held the Ce(IV) ion by the bridging oxide ions. Magnetization and magnetic susceptibility studies establish that 1 has an S = 16 spin ground state, the largest yet for a Mn cluster, and displays the slow magnetization relaxation and hysteresis behavior of a single-molecule magnet (SMM). It is thus the highest spin Mn SMM discovered to date. Copyright © 2003 American Chemical Society.en
dc.sourceJournal of the American Chemical Societyen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-0347480558&doi=10.1021%2fja0385134&partnerID=40&md5=4bd9e53e97961d9a903b105a45e69883
dc.subjectarticleen
dc.subjectsynthesisen
dc.subjectmagnetismen
dc.subjectmolecular interactionen
dc.subjectcrystallizationen
dc.subjectmanganese derivativeen
dc.subjectstructure analysisen
dc.subjecttechniqueen
dc.subjectchemical structureen
dc.subjectanisotropyen
dc.subjectchemical reactionen
dc.subjectpolymeren
dc.subjectquantum mechanicsen
dc.subjecthydrogen bonden
dc.subjectparameteren
dc.subjectceriumen
dc.subjectmagneten
dc.subjectaccelerationen
dc.subjectoxygen derivativeen
dc.titleTemplate Synthesis and Single-Molecule Magnetism Properties of a Complex with Spin S = 16 and a [Mn8O8]8+ Saddle-Like Coreen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1021/ja0385134
dc.description.volume125
dc.description.issue50
dc.description.startingpage15274
dc.description.endingpage15275
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :82</p>en
dc.source.abbreviationJ.Am.Chem.Soc.en
dc.contributor.orcidTasiopoulos, Anastasios J. [0000-0002-4804-3822]
dc.gnosis.orcid0000-0002-4804-3822


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